VITEEE 2013 Question Paper is available for download here. VITEEE 2013 Question Paper includes 40 questions from Mathematics/Biology, 35 questions from Physics, 35 questions from Chemistry, 5 questions from English, 10 questions from Aptitude to be attempted in 150 minutes. Candidates can download the VITEEE 2013 Question Paper with Solution PDF using the link below.

VITEEE 2013 Question Paper with Solution PDF

VITEEE 2013 Question Paper with Solution PDF Download PDF Check Solution

Question 1:

The amplitude of an electromagnetic wave in vacuum is doubled with no other changes made to the wave. As a result of this doubling of the amplitude, which of the following statement is correct?

  • (1) The frequency of the wave changes only
  • (2) The wave length of the wave changes only
  • (3) The speed of the wave propagation changes only
  • (4) Alone of the above is correct

Question 2:

An element with atomic number \( Z = 11 \) emits \( K_{\alpha} \)-X-ray of wavelength \( \lambda \). The atomic number which emits \( K_{\alpha} \)-X-ray of wavelength \( 4\lambda \) is

  • (1) 4
  • (2) 6
  • (3) 11
  • (4) 44

Question 3:

Mobilities of electrons and holes in a sample of intrinsic germanium at room temperature are \( 0.36 \, m^2 \, V^{-1} \, s^{-1} \) and \( 0.17 \, m^2 \, V^{-1} \, s^{-1} \), respectively. The electron and hole densities are each equal to \( 2.5 \times 10^{19} \, m^{-3} \). The electrical conductivity of germanium is

  • (1) 4.24 S/m
  • (2) 2.12 S/m
  • (3) 1.09 S/m
  • (4) 0.47 S/m

Question 4:

If a radio-receiver amplifies all the signal frequencies equally well, it is said to have high

  • (1) Sensitivity
  • (2) Selectivity
  • (3) Distortion
  • (4) Fidelity

Question 5:

If a progressive wave is represented as \[ y = 2 \sin \left( \pi \left( \frac{t}{2} - \frac{x}{4} \right) \right) \]
where \( x \) is in meters and \( t \) is in seconds, then the distance traveled by the wave in 5 s is

  • (1) 5 m
  • (2) 10 m
  • (3) 25 m
  • (4) 32 m

Question 6:

The gravitational potential at a place varies inversely with \( x^2 \) (i.e., \( V = kx^2 \)), the gravitational field at that place is

  • (1) \( \frac{2k}{x^3} \)
  • (2) \( \frac{-2k}{x^3} \)
  • (3) \( \frac{k}{x} \)
  • (4) \( \frac{-k}{x} \)

Question 7:

A copper wire of length 2.2 m and a steel wire of length 1.6 m, both of diameter 3.0 mm, are connected end to end. When stretched by a force, the elongation in length 0.50 m is produced in the copper wire. The stretching force is ( \( Y_{cu} = 1.1 \times 10^{11} \, N/m^2, Y_{steel} = 2.0 \times 10^{11} \, N/m^2 \))

  • (1) \( 5.4 \times 10^2 \, N \)
  • (2) \( 3.6 \times 10^2 \, N \)
  • (3) \( 2.4 \times 10^2 \, N \)
  • (4) \( 1.8 \times 10^2 \, N \)

Question 8:

If \( v_p, v_{rms}, v_p \) represent the mean speed, root mean square speed, and most probable speed of the molecules in an ideal monoatomic gas at temperature \( T \) and \( m \) is the mass of the molecule, then

  • (1) \( v_p < v_{rms} < v_p \)
  • (2) No molecule can have a speed greater than \( \sqrt{2} v_{rms} \)
  • (3) No molecule can have a speed less than \( v_p/\sqrt{2} \)
  • (4) None of the above

Question 9:

Two balls of equal masses are thrown upwards along the same vertical direction at an interval of 2 s, with the same initial velocity of 39.2 m/s. The two balls will collide at a height of

  • (1) 39.2 m
  • (2) 73.5 m
  • (3) 78.4 m
  • (4) 117.6 m

Question 10:

The dimensional formula of magnetic flux is

  • (1) \( [M L^2 T^{-1} A^{-2}] \)
  • (2) \( [M L^2 T^{-2} A^{-1}] \)
  • (3) \( [M L^2 T^{-1} A^{-1}] \)
  • (4) \( [M L^0 T^{-2} A^{-1}] \)

Question 11:

The time dependence of a physical quantity \( P \) is given by \( P = P_0 e^{\alpha (-\alpha t^2)} \), where \( \alpha \) is a constant and \( t \) is time. The constant \( \alpha \) has dimensions of

  • (1) is dimensionless
  • (2) has dimensions of \( P \)
  • (3) has dimensions of \( T^2 \)
  • (4) has dimensions of \( T \)

Question 12:

If the potential energy of a gas molecule is \[ U = \frac{M}{r} - \frac{N}{r^2} \]
where \( M \) and \( N \) are positive constants, then the potential energy at equilibrium must be

  • (1) zero
  • (2) \( \frac{MN}{4} \)
  • (3) \( \frac{MN^2}{4} \)
  • (4) zero

Question 13:

A table fan rotating at a speed of 2400 rpm is switched off and the resulting variation of revolution per minute with time is shown in figure. The total number of revolutions of the fan before it comes to rest is

  • (1) 160
  • (2) 380
  • (3) 420
  • (4) 480

Question 14:

In the adjoining figure, the position-time graph of a particle of mass 0.1 kg is shown. The impulse at \( t = 2 \) s is

  • (1) 0.02 kg m/s
  • (2) 0.1 kg m/s
  • (3) 0.2 kg m/s
  • (4) 0.4 kg m/s

Question 15:

The pressure on a square plate is measured by measuring the force on the plate. If the maximum error in the measurement of force and length are 4% and 2%, then the maximum error in the measurement of pressure is

  • (1) 1%
  • (2) 2%
  • (3) 3%
  • (4) 4%

Question 16:

The centre of a wheel rolling on a plane surface moves with a speed \( v_0 \). A particle on the rim of the wheel at the same level as the centre will be moving at speed

  • (1) zero
  • (2) \( v_0 \)
  • (3) \( 2v_0 \)
  • (4) \( \sqrt{2} v_0 \)

Question 17:

A body of mass \( 5 \, m \) initially at rest explodes into 3 fragments with mass ratio 3:1:1. Two of the fragments each of mass \( m \) are found to move with a speed of \( 60 \, m/s \) in mutually perpendicular directions. The velocity of the third fragment is

  • (1) \( 10 \sqrt{5} \, m/s \)
  • (2) \( 20 \sqrt{5} \, m/s \)
  • (3) \( 60 \, m/s \)
  • (4) \( 60 \, m/s \)

Question 18:

A body of mass 2 kg moving with a velocity of \( 6 \, m/s \) strikes elastically with another body of mass 4 kg initially at rest. The amount of heat evolved during this collision is

  • (1) 183 J
  • (2) 6 J
  • (3) 9 J
  • (4) 3 J

Question 19:

Two particles of equal mass \( m \) go round a circle of radius \( R \) under the action of their mutual gravitational attraction. The speed of each particle is

  • (1) \( \sqrt{\frac{GM}{R}} \)
  • (2) \( \sqrt{\frac{GM}{R^2}} \)
  • (3) \( \sqrt{\frac{GM}{R^3}} \)
  • (4) \( \sqrt{\frac{GM}{R}} \)

Question 20:

Four equal charges \( Q \) each are placed at four corners of a square of side \( a \). Work done in carrying a charge \( -q \) from its centre to infinity is

  • (1) zero
  • (2) \( \frac{\sqrt{2} q}{\pi \epsilon_0 a} \)
  • (3) \( \frac{q^2}{2 \pi \epsilon_0 a} \)
  • (4) \( \frac{q^2}{\pi \epsilon_0 a} \)

Question 21:

A network of resistances, cell and capacitor \( C = (2 + 4) \, F \) is shown in the adjoining figure. In steady state condition, the charge on \( 2 \, F \) capacitor is \( Q \), while \( R \) is unknown resistance. Values of \( Q \) and \( R \) are respectively

  • (1) \( 4 \, \mu C \) and \( 10 \, \Omega \)
  • (2) \( 4 \, \mu C \) and \( 4 \, \Omega \)
  • (3) \( 2 \, \mu C \) and \( 4 \, \Omega \)
  • (4) \( 2 \, \mu C \) and \( 8 \, \Omega \)

Question 22:

As the electron in Bohr’s orbit of hydrogen atom passes from state \( n = 2 \) to \( n = 1 \), the KE (K) and the potential energy (U) changes as

  • (1) \( K \) fourfold, \( U \) also fourfold
  • (2) \( K \) twofold, \( U \) also twofold
  • (3) \( K \) fourfold, \( U \) twofold
  • (4) \( K \) twofold, \( U \) fourfold

Question 23:

To get an OR gate from a NAND gate, we need

  • (1) Only two NAND gates
  • (2) Two NOT gates obtained from NAND gates and one NAND gate
  • (3) Four NAND gates and two AND gates obtained from NAND gates
  • (4) None of the above

Question 24:

If a current \( I \) is flowing in a loop of radius \( r \) as shown in the adjoining figure, then the magnetic field induction at the center O will be

  • (1) Zero
  • (2) \( \frac{\mu_0 I}{4 \pi r} \)
  • (3) \( \frac{2 \mu_0 I}{4 \pi r} \)
  • (4) \( \frac{\mu_0 I}{2 \pi r} \)

Question 25:

Two identical magnetic dipoles of magnetic moment \( 1.0 \, Am^2 \) each, placed at a separation of 2 m with their axes perpendicular to each other. The resultant magnetic field at a point midway between the dipoles is

  • (1) \( 5 \times 10^{-7} \, T \)
  • (2) \( 2 \times 10^{-7} \, T \)
  • (3) \( 1 \times 10^{-7} \, T \)
  • (4) \( 4 \times 10^{-7} \, T \)

Question 26:

The natural frequency of the circuit shown in adjoining figure is

  • (1) \( \frac{1}{2 \pi \sqrt{LC}} \)
  • (2) \( \frac{1}{2 \pi \sqrt{2LC}} \)
  • (3) \( \frac{2}{\pi \sqrt{LC}} \)
  • (4) zero

Question 27:

A lead shot of 1 mm diameter falls through a long column of glycerine. The variation of the velocity with distance covered (s) is correctly represented by


Question 28:

If \( \epsilon_0 \) and \( \mu_0 \) represent the permittivity and permeability of vacuum and \( \epsilon \) and \( \mu \) represent the permittivity and permeability of medium, then refractive index of the medium is given by

  • (1) \( \frac{\epsilon}{\epsilon_0} \)
  • (2) \( \frac{\mu}{\mu_0} \)
  • (3) \( \sqrt{\frac{\epsilon}{\epsilon_0}} \)
  • (4) \( \sqrt{\frac{\mu}{\mu_0}} \)

Question 29:

A student plots a graph between inverse of magnification \( \frac{1}{m} \) produced by a convex thin lens and the object distance \( u \) as shown in figure. What was the focal length of the lens used?

  • (1) \( \frac{b}{c} \)
  • (2) \( \frac{b}{a} \)
  • (3) \( \frac{a}{b} \)
  • (4) \( \frac{c}{b} \)

Question 30:

Two waves \( y_1 = A_1 \sin (\omega t - \beta_1 x) \) and \( y_2 = A_2 \sin (\omega t - \beta_2 x) \) superimpose to form a resultant wave whose amplitude is

  • (1) \( A_1 + A_2 \)
  • (2) \( \sqrt{A_1^2 + A_2^2} \)
  • (3) \( A_1^2 + A_2^2 \)
  • (4) \( \sqrt{A_1^2 + A_2^2 + 2 A_1 A_2 \cos (\beta_2 - \beta_1)} \)

Question 31:

When a certain metallic surface is illuminated with monochromatic light of wavelength \( \lambda \), the stopping potential for photoelectric current is \( V_0 \). When the same surface is illuminated with a light of wavelength \( 2\lambda \), the stopping potential is \( V_1 \). The threshold wavelength for this surface to photoelectric effect is

  • (1) \( \lambda_0 \)
  • (2) \( 6\lambda \)
  • (3) \( \frac{4\lambda}{3} \)
  • (4) \( \frac{3\lambda}{4} \)

Question 32:

In the \( I-V \) diagram shown in adjoining figure, what is the relation between \( P_1 \) and \( P_2 \)?

  • (1) \( P_2 = P_1 \)
  • (2) \( P_2 < P_1 \)
  • (3) \( P_2 > P_1 \)
  • (4) Insufficient data

Question 33:

If a gas mixture contains 2 moles of O\(_2\) and 4 moles of Ar at temperature \( T \), then what will be the total energy of the system (neglecting all vibrational modes)?

  • (1) \( 11 RT \)
  • (2) \( 15 RT \)
  • (3) \( 8 RT \)
  • (4) \( 7 RT \)

Question 34:

In the adjoining figure, two pulses in a stretched string are shown. If initially their centres are 8 cm apart and they are moving towards each other, with speed of 2 cm/s, then total energy of the pulses after 2 s will be

  • (1) Zero
  • (2) Purely kinetic
  • (3) Purely potential
  • (4) Partly kinetic and partly potential

Question 35:

When two waves of almost equal frequency \( n_1 \) and \( n_2 \) are produced simultaneously, then the time interval between successive maxima is

  • (1) \( \frac{1}{n_1 + n_2} \)
  • (2) \( \frac{1}{n_1} - \frac{1}{n_2} \)
  • (3) \( \frac{1}{n_1 n_2} \)
  • (4) \( \frac{1}{n_1 - n_2} \)

Question 36:

A long glass capillary tube is dipped in water. It is known that water wets glass. The water level rises by \( h \) in the tube. The tube is now pushed down so that only a length \( h/2 \) is outside the water surface. The angle of contact at the water surface at the upper end of the tube will be

  • (1) \( 30^\circ \)
  • (2) \( 60^\circ \)
  • (3) \( 15^\circ \)
  • (4) \( 45^\circ \)

Question 37:

In the adjoining circuit, if reading of voltmeter \( V_1 \) and \( V_2 \) are 300 volts, each, then the reading voltmeter \( V_3 \) and ammeter \( A \) are respectively

  • (1) \( 220 \, V, 2.2 \, A \)
  • (2) \( 220 \, V, 2.0 \, A \)
  • (3) \( 100 \, V, 2.2 \, A \)
  • (4) \( 100 \, V, 2.0 \, A \)

Question 38:

If the work done in turning a magnet of magnetic moment \( M \) by an angle of \( 90^\circ \) from the magnetic meridian is in times the corresponding work done to turn it through an angle of \( 60^\circ \), then the value of \( n \) is

  • (1) \( 1 \)
  • (2) \( 1/2 \)
  • (3) \( 2 \)
  • (4) \( 1/4 \)

Question 39:

The capacitance of a parallel plate capacitor with air as dielectric is \( C \). If a slab of dielectric constant \( K \) and of the same thickness as the separation between the plates is introduced so as to fill \( \frac{1}{4} \)th of the capacitor (shown in figure), then the new capacitance is

  • (1) \( (K+1) \frac{C}{4} \)
  • (2) \( (K+3) \frac{C}{4} \)
  • (3) \( (K+1) \frac{C}{2} \)
  • (4) None of these

Question 40:

Seven resistances are connected between points A and B as shown in adjoining figure. The equivalent resistance between A and B is

  • (1) 5 \( \Omega \)
  • (2) 4 \( \Omega \)
  • (3) 3 \( \Omega \)
  • (4) 4.5 \( \Omega \)

Question 41:

Which of the following does not undergo benzoin condensation?


Question 42:

The reaction between COOH and NaHCO\(_3\) is:



Question 43:

Benzene diazonium chloride on treatment with hypophosphorous acid and water yields benzene. Which of the following is used as a catalyst in this reaction?

  • (1) \( LiAlH_4 \)
  • (2) Red P
  • (3) \( Zn \)
  • (4) \( Cu \)

Question 44:

Consider the following reaction sequence:
 

Isomers are:

  • (1) \( C \) and \( E \)
  • (2) \( C \) and \( D \)
  • (3) \( D \) and \( E \)
  • (4) \( C \) and \( D \)

Question 45:

When a monosaccharide forms a cyclic hemiacetal, the carbon atom that contained the carbonyl group is identified as the … carbon atom, because

  • (1) The carbonyl group is drawn to the right
  • (2) The carbonyl group is drawn to the left
  • (3) Acetal forms bond to an -OR and an —OH
  • (4) Anomeric, its substituents can assume an \( \alpha \) or \( \beta \) position

Question 46:

Which of the following is/are \( \alpha \)-amino acid?


Question 47:

Calculate pH of a buffer prepared by adding 10 mL of 0.10 M acetic acid to 20 mL of 1 M sodium acetate [\( CH_3COOH \)] at \( pH = 4.74 \).

  • (1) 3.00
  • (2) 4.44
  • (3) 4.74
  • (4) 5.04

Question 48:

The equivalent conductance of silver nitrate solution at 250°C for an infinite dilution was found to be \( 133.30 \, S cm^2 equiv^{-1} \). The transport number of \( Ag^+ \) ions in very dilute solution of \( AgNO_3 \) is 0.464. Equivalent conductances of \( Ag^+ \) and \( NO_3^- \) at infinite dilution are respectively

  • (1) \( 1952, 1333 \)
  • (2) \( 714, 619.4 \)
  • (3) \( 1952, 1333 \)
  • (4) \( 616, 1952 \)

Question 49:

Treating anisole with the following reagents, the major product obtained is
I. \( CH_3 \), CCl\(_3\), II. Cl\(_2\), FeCl\(_3\), III. HBr, Heat


Question 50:

Ketones \( [R-C(R)=O] \), where \( R = alkyl \) group can be obtained in one step by

  • (1) Hydrolysis of esters
  • (2) Oxidation of primary alcohols
  • (3) Oxidation of secondary alcohols
  • (4) Reaction of acid halide with alcohols

Question 51:

An optically active compound \( X \) has molecular formula \( C_4H_8O_3 \), it evolves \( CO_2 \) with aqueous NaHCO\(_3\). \( X \) reacts with LiAlH\(_4\) to give an achiral compound. \( X \) is

  • (1) \( CH_3COOH \)
  • (2) \( CH_3 CHO \)
  • (3) \( CH_3 COOH \)
  • (4) \( C_6 H_5 COOH \)

Question 52:

Product is/are



Question 53:

Glycerol \( C_3 H_8 O_3 \) reacts with \(HCl \), the product A is obtained. What is the structure of A?


Question 54:

Phenol is heated with phthalic anhydride in the presence of cone. H\(_2\)SO\(_4\). The product gives pink colour with alkaline ferric chloride. The product is

  • (1) Salicylic acid
  • (2) Bakelite
  • (3) Phenolphthalein
  • (4) Fluorescein

Question 55:

\( \gamma \) \( H_2 O \) → \( Z \) is identified as

  • (1) \( CH_3 COOH \)
  • (2) \( CH_3 NH_2 \)
  • (3) \( CH_2 OH \)
  • (4) None of these

Question 56:

B can be obtained from halide by van-Arkel method. This involves reaction

  • (1) \( B \) + \( Red I_2 \) → \( B_2 \) + 3I
  • (2) \( B \) + \( 3 H_2 \) → \( B_2 \) + 6HCl
  • (3) \( B \) + \( 3 H_2 \) → \( B_2 \) + 3H
  • (4) \( B_2 \) + 3\( Cl_2 \)

Question 57:

\( NH_4 Cl \) is heated in a test tube. Vapours are brought in contact with red litmus paper, which changes it to blue and then to red. It is because of

  • (1) formation of \( NH_3 \) and HCl
  • (2) formation of \( N_2 \) and HCl
  • (3) greater diffusion of \( NH_3 \) than HCl
  • (4) greater diffusion of HCl than \( NH_3 \)

Question 58:

Out of \( H_2 SO_4 \), \( H_2 SO_3 \), \( H_2 S_2 O_8 \), peroxy acids are

  • (1) \( H_2 SO_5 \)
  • (2) \( H_2 SO_4 \)
  • (3) \( H_2 SO_3 \)
  • (4) \( H_2 S_2 O_8 \)

Question 59:

The density of solid argon is 1.65 g per cc at 233°C. If the argon atom is assumed to be a sphere of radius \( 1.54 \times 10^{-8} \) cm, what percent of solid argon is apparently empty space? \( A_r = 40 \)

  • (1) 16.5%
  • (2) 38%
  • (3) 50%
  • (4) 62%

Question 60:

When 1 mole of CO\(_2\) occupying volume 10L at 27°C is expanded under adiabatic condition, temperature falls to 150 K. Hence, final volume is

  • (1) 5L
  • (2) 20L
  • (3) 40L
  • (4) 80L

Question 61:

Acid hydrolysis of ester is first order reaction and rate constant is given by \[ k = \frac{2.303}{t} \log \frac{V_0 - V}{V_0 - V_t} \]
where \( V_0 \), \( V_t \), and \( V_\infty \) are the volume of standard NaOH required to neutralise acid present at a given time, if ester is 50% neutralised then

  • (1) \( V_t = V_0 \)
  • (2) \( V_t = 2V_0 \)
  • (3) \( V_\infty = V_t \)
  • (4) \( V_\infty = 2V_t \)

Question 62:

A near UV photon of 300 nm is absorbed by a gas and then re-emitted as two photons. One photon is red with wavelength of the second photon is

  • (1) 1060nm
  • (2) 496nm
  • (3) 300nm
  • (4) 215nm

Question 63:

Which of these ions is expected to be coloured in aqueous solution?

  • (1) Fe\(^{3+} \)
  • (2) Ni\(^{2+} \)
  • (3) Al\(^{3+} \)
  • (4) I and III

Question 64:

Select the correct statements(s)

  • (1) \( LiAlH_4 \) reduces methyl cyanide to methyl amine
  • (2) Alkane nitrile has electrophilic as well as nucleophilic centers
  • (3) Saponification is a reversible reaction
  • (4) Alkaline hydrolysis of methane nitrile forms methanoic acids

Question 65:

The product Y is

  • (1) p-chloro nitrobenzene
  • (2) o-chloro nitrobenzene
  • (3) m-chloro nitrobenzene
  • (4) o, p-dichloro nitrobenzene

Question 66:

End product of the following reaction is


Question 67:

Following compounds are respectively ... geometrical isomers

  • (1) \( cis \), \( cis \), \( trans \)
  • (2) \( cis \), \( trans \), \( trans \)
  • (3) \( trans \), \( trans \), \( cis \)
  • (4) \( cis \), \( cis \), \( cis \)

Question 68:

Which is more basic oxygen in an ester?

  • (1) Carbonyl oxygen, \( \alpha \)
  • (2) Carboxyl oxygen, \( \beta \)
  • (3) Equally basic
  • (4) Both are acidic oxygen

Question 69:

In a Claisen condensation reaction (when an ester is treated with a strong base)

  • (1) A proton is removed from the \( \alpha \)-carbon to form a resonance stabilized carbanion of the ester.
  • (2) Carbanion acts as a nucleophile in a nucleophilic acyl substitution reaction with another ester molecule.
  • (3) A new \( C-C \) bond is formed.
  • (4) All of the above statements are correct.

Question 70:

An organic compound \( B \) is formed by the reaction of ethyl magnesium iodide with a substance \( A \), followed by treatment with dilute aqueous acid. Compound \( B \) does not react with PCC or PDC in dichloromethane. Which of the following is a possible compound for \( A \)?

  • (1) \( CH_3COOH \)
  • (2) \( CH_3 CHO \)
  • (3) \( CH_3 COOH \)
  • (4) \( H_2C=O \)

Question 71:

\( CH_3CH_2CH_2COCH_3 \) reacts with \( CH_3 MgBr \) (one mole) followed by treatment with \( H_2 O \). The compound \( A \) formed in this reaction is


Question 72:

For the cell reaction \( 2Cu^{2+} + Co \rightarrow 2Co^{2+} + Cu \), \( E^\circ_{cell} \) is 1.89V. If \( E^\circ_{Co^{2+}/Co} \) is -0.28V, what is the value of \( E^\circ_{Cu^{2+}/Cu} \)?

  • (1) 0.28V
  • (2) 1.61V
  • (3) 2.17V
  • (4) 1.0V

Question 73:

A constant current of 30 A is passed through an aqueous solution of NaCl for a time of 1.00 h. What is the volume of Cl\(_2\) gas at STP produced?

  • (1) 30.0L
  • (2) 25.0L
  • (3) 12.5L
  • (4) 11.2L

Question 74:

Consider the following reaction:
 

  • (1) \( li \) is the correct label for the reaction.
  • (2) The structure is based on certain conditions.
  • (3) Possible outcome in higher reaction scenarios.
  • (4) None of these is relevant.

Question 75:

The reaction of zinc with \( Cu^{2+} \) produces the following.
Entropy change \( \Delta S \) is given by \( 96.5 J \cdot mol^{-1} \cdot K^{-1} \).

  • (1) \( 2 \times 10^4 \, V \, K^{-1} \)
  • (2) \( 10 \times 10^3 \, V \, K^{-1} \)
  • (3) \( 5 \times 10^4 \, V \, K^{-1} \)
  • (4) \( 9.65 \times 10^4 \, V \, K^{-1} \)

Question 76:

What transition in the hydrogen spectrum would have the same wavelength as the Balmer transition, \( n = 4 \) to \( n = 2 \) of He\(^+\) spectrum?

  • (1) \( n = 4 \) to \( n = 2 \)
  • (2) \( n = 3 \) to \( n = 2 \)
  • (3) \( n = 2 \) to \( n = 1 \)
  • (4) \( n = 3 \) to \( n = 3 \)

Question 77:

What is the degeneracy of the level of H-atom that has energy \( \frac{R_H}{9} \)?

  • (1) 16
  • (2) 9
  • (3) 4
  • (4) 1

Question 78:

Match the following and choose the correct option given below.
Compound/Type \(\quad\) Use
A. Dry ice 1. Anti-knocking compound
B. Semiconductor 2. Electronic diode or triode
C. Solder 3. Joining circuits
D. TEL 4. Refrigerant for preserving food

  • (1) A B C D
  • (2) I II III IV
  • (3) II III IV I
  • (4) IV III II I

Question 79:

Which of the following ligands is tetradentate?




Question 80:

What is the EAN of \( [Al(C_4O_4)_3]^{3-} \)?

  • (1) 28
  • (2) 22
  • (3) 16
  • (4) 10

Question 81:

The relation \( R \) defined on set \( A = \{x : |x| < 3, x \in \mathbb{R} \} \) by \( R = \{(x, y): y = |x|\} \) is

  • (1) \( \{(2, 2), (1, 1), (0, 0), (1, 1), (2, 2)\} \)
  • (2) \( \{(2, -2), (-2, -2), (1, 1), (0, 0), (1, -2)\} \)
  • (3) \( \{(0, 0), (1, 1), (2, 2)\} \)
  • (4) None of the above

Question 82:

The solution of the differential equation \[ \frac{dy}{dx} = \frac{y}{f(x)} - y^2 \]
is

  • (1) \( f(x) = y + C \)
  • (2) \( f(x) = y + C + C \)
  • (3) \( f(x) = y + C \)
  • (4) None of the above

Question 83:

If \( a \), \( b \), and \( c \) are in AP, then determinant
\[ \begin{vmatrix} x+2 & x+3 & x+4
x+4 & x+5 & x+6
x+7 & x+8 & x+9 \end{vmatrix} \]

  • (1) 0
  • (2) 1
  • (3) \( x \)
  • (4) \( 2x \)

Question 84:

If two events A and B. If odds against A are 2:1 and those in favour of \( A \cup B \) are 3:1, then

  • (1) \( \frac{1}{2} \leq P(B) \leq \frac{3}{4} \)
  • (2) \( \frac{5}{12} \leq P(B) \leq \frac{3}{4} \)
  • (3) \( \frac{1}{5} \leq P(B) \leq \frac{3}{4} \)
  • (4) None of these

Question 85:

The value of \( 2 \tan^{-1} x - \left( cosec \, \tan^{-1} x - \tan \, \cot \, x \right) \)

  • (1) \( \tan^{-1} x \)
  • (2) \( \tan x \)
  • (3) \( \cot x \)
  • (4) \( cosec^{-1} x \)

Question 86:

The proposition \( \neg (p \iff q) \) is equivalent to

  • (1) \( (p \vee \neg q) \land (q \vee \neg p) \)
  • (2) \( (p \vee q) \land (\neg p \vee \neg q) \)
  • (3) \( (p \neg q) \lor (q \neg p) \)
  • (4) None of the above

Question 87:

If truth values of \( p \) be F and \( q \) be T, then truth value of \( \neg(p \vee q) \) is

  • (1) T
  • (2) F
  • (3) Either T or F
  • (4) Neither T nor F

Question 88:

The rate of change of the surface area of a sphere of radius \( r \), when the radius is increasing at the rate of \( 2 \, cm/s \), is proportional to

  • (1) \( \frac{1}{r} \)
  • (2) \( \frac{1}{r^2} \)
  • (3) \( r^2 \)
  • (4) \( r^3 \)

Question 89:

If \( N \) denote the set of all natural numbers and \( R \) the relation on \( N \times N \) defined by \( (a, b) R (c, d) \), if \( a(b + c) = b(a + d) \), then \( R \) is

  • (1) symmetric only
  • (2) reflexive only
  • (3) transitive only
  • (4) an equivalence relation

Question 90:

A complex number \( z \) is such that \( \arg \left( \frac{-2}{3} + \frac{2i}{3} \right) = \frac{\pi}{3} \). The points representing this complex number will lie on

  • (1) an ellipse
  • (2) a parabola
  • (3) a circle
  • (4) a straight line

Question 91:

If \( a_1, a_2, a_3 \) be any positive real numbers, then which of the following statement is true?

  • (1) \( 3a_1a_2a_3 \leq a_1^2 + a_2^2 + a_3^2 \)
  • (2) \( a_1^2 + a_2^2 + a_3^2 \geq 3a_1a_2a_3 \)
  • (3) \( a_1a_2a_3 \geq \frac{a_1^2 + a_2^2 + a_3^2}{3} \)
  • (4) \( a_1 + a_2 + a_3 \geq \frac{a_1^2 + a_2^2 + a_3^2}{3} \)

Question 92:

If \( x^2 + 2x - 5 = 0 \), then the values of \( x \) are

  • (1) \( 2, 2, -4 \)
  • (2) \( -2, 2, 4 \)
  • (3) \( -3, 2, 5 \)
  • (4) \( -2, -1, 3 \)

Question 93:

The centres of a set of circles, each of radius 3, lie on the circle \( x^2 + y^2 = 25 \). The locus of any point in the set is

  • (1) \( x^2 + y^2 = 25 \)
  • (2) \( x^2 + y^2 = 3 \)
  • (3) \( x^2 + y^2 = 6 \)
  • (4) None of these

Question 94:

A tower \( A \) leans towards west making an angle \( \theta \) with the vertical. The angular elevation of \( B \), the topmost point of the tower is \( \beta \) as observed from a point \( C \) at a distance \( d' \) from \( B \). If the angular elevation of \( B \) from point \( D \) due east of \( C \) is the same and \( 2d \) from \( C \), then \( \theta \) can be given as

  • (1) \( \tan \theta = \frac{2}{3} \)
  • (2) \( \tan \theta = \frac{3}{2} \)
  • (3) \( \tan \theta = \frac{1}{2} \)
  • (4) \( \tan \theta = \frac{1}{3} \)

Question 95:

\( \theta \) and \( \gamma \) are the roots of the equation \( x^2 - \alpha x + \beta = 0 \) and if \( \theta + \gamma = \alpha \), then what is the value of \( \theta^2 + \gamma^2 \)?

  • (1) \( \alpha^2 - 2\beta \)
  • (2) \( \alpha^2 + 2\beta \)
  • (3) \( \alpha^2 - 4\beta \)
  • (4) \( \alpha^2 + 4\beta \)

Question 96:

The angle of intersection of the circles \( x^2 + y^2 - 8x - 9 = 0 \) and \( x^2 + y^2 + 2x - 4y - 11 = 0 \) is

  • (1) \( \tan^{-1} \left( \frac{9}{8} \right) \)
  • (2) \( \tan^{-1} \left( 19 \right) \)
  • (3) \( \tan^{-1} \left( 5 \right) \)
  • (4) \( \tan^{-1} \left( 1 \right) \)

Question 97:

Which of the following is the correct expansion of the series
\[ \sum_{n=0}^{\infty} \left( \binom{C}{n} \right) \left( \frac{3}{5} \right)^n \left( \frac{2}{5} \right)^{n+1} \]

  • (1) \( 2 \times 10^4 \)
  • (2) \( 2 \times 10^5 \)
  • (3) \( 10^6 \)
  • (4) \( 9 \times 10^4 \)

Question 98:

The vector \( \mathbf{r} = 3\hat{i} + 4\hat{k} \) can be written as the sum of a vector \( \mathbf{v} \), parallel to \( \hat{i} + \hat{k} \), and a vector \( \mathbf{u} \), perpendicular to \( \hat{i} + \hat{k} \). Then, the value of \( \mathbf{v} \) is

  • (1) \( \mathbf{v} = 3\hat{i} + 2\hat{k} \)
  • (2) \( \mathbf{v} = 4\hat{i} + \hat{k} \)
  • (3) \( \mathbf{v} = \hat{i} + 4\hat{k} \)
  • (4) \( \mathbf{v} = 3\hat{i} + \hat{k} \)

Question 99:

If the points \( (x_1, y_1) \), \( (x_2, y_2) \), and \( (x_3, y_3) \) are collinear, then the rank of the matrix
\[ \begin{bmatrix} x_1 & y_1 & 1
x_2 & y_2 & 1
x_3 & y_3 & 1 \end{bmatrix} \]

  • (1) Will always be less than 3
  • (2) 2
  • (3) 1
  • (4) None of these

Question 100:

The value of the determinant
\[ \begin{vmatrix} \cos(\alpha - \beta) & \cos \alpha & \cos \beta
\cos(\alpha - \beta) & 1 & \cos \beta
\cos \alpha & \cos \beta & 1 \end{vmatrix} \]

  • (1) \( \alpha^2 + \beta^2 \)
  • (2) \( \alpha^2 - \beta^2 \)
  • (3) \( 1 \)
  • (4) None of these

Question 101:

The number of integral values of \( K \), for which the equation \( 7 \cos x + 5 \sin x = 2K + 1 \) has a solution, is

  • (1) 4
  • (2) 8
  • (3) 10
  • (4) 2

Question 102:

The line joining two points \( A(2,0) \), \( B(3,1) \) is rotated about \( A \) in anti-clockwise direction through an angle of \( 15^\circ \). The equation of the line in the new position is

  • (1) \( \sqrt{3}x - y - 2\sqrt{5} = 0 \)
  • (2) \( x - 3y - 2 = 0 \)
  • (3) \( \sqrt{3}x + y - 2\sqrt{5} = 0 \)
  • (4) \( x + y - 2 = 0 \)

Question 103:

The line \( 2x + \sqrt{6}y = 2 \) is tangent to the curve \( x^2 - 2y^2 = 4 \). The point of contact is

  • (1) \( (4, -6) \)
  • (2) \( (3, -6) \)
  • (3) \( (7, -6) \)
  • (4) \( (2, -6) \)

Question 104:

The number of integral points (integral point means both the coordinates should be integers) exactly in the interior of the triangle with vertices \( (0, 0), (0, 21), (21, 0) \) is

  • (1) 100
  • (2) 150
  • (3) 105
  • (4) 120

Question 105:

\( \int (x + 1)(x - x^2) e^x \, dx \) is equal to

  • (1) \( (x + 1)e^x + C \)
  • (2) \( (x - 1)e^x + C \)
  • (3) \( e^x + C \)
  • (4) \( (x + 1)e^x + C \)

Question 106:

If \( f(x) = x - \lfloor x \rfloor \), for every real number \( x \), where \( \lfloor x \rfloor \) is the integral part of \( x \), then
\[ \int f(x) \, dx \]

is equal to

  • (1) \( 0 \)
  • (2) \( \frac{1}{2} \)
  • (3) \( \frac{1}{3} \)
  • (4) \( \frac{1}{2} \)

Question 107:

The value of the integral
\[ \int_1^\infty \frac{x+1}{|x-1|} \left( \frac{x-1}{x+1} \right)^{1/2} \, dx \]

is

  • (1) \( \log 3 \)
  • (2) \( 4 \log 3 \)
  • (3) \( 4 \log 4 \)
  • (4) \( \log 4 \)

Question 108:

If a tangent having slope \( \frac{-4}{3} \) to the ellipse
\[ \frac{x^2}{18} + \frac{y^2}{32} = 1 \]

intersects the major and minor axes in points A and B respectively, then the area of \( \triangle OAB \) is equal to

  • (1) 48 sq units
  • (2) 32 sq units
  • (3) 24 sq units
  • (4) 64 sq units

Question 109:

The locus of mid points of tangents intercepted between the axes of ellipse
\[ \frac{x^2}{a^2} + \frac{y^2}{b^2} = 1 \]

is

  • (1) \( \frac{x^2}{a^2} + \frac{y^2}{b^2} = 2 \)
  • (2) \( \frac{x^2}{a^2} + \frac{y^2}{b^2} = 1 \)
  • (3) \( \frac{x^2}{a^2} + \frac{y^2}{b^2} = 4 \)
  • (4) \( \frac{x^2}{a^2} + \frac{y^2}{b^2} = 3 \)

Question 110:

If \( P \) is a double ordinate of hyperbola
\[ \frac{x^2}{a^2} - \frac{y^2}{b^2} = 1 \]

such that \( OPQ \) is an equilateral triangle, \( O \) being the centre of the hyperbola, then the eccentricity \( e \) of the hyperbola satisfies

  • (1) \( 1 < e < \frac{2}{\sqrt{3}} \)
  • (2) \( e = \frac{2}{\sqrt{3}} \)
  • (3) \( e = \frac{\sqrt{3}}{2} \)
  • (4) \( e > \frac{2}{\sqrt{3}} \)

Question 111:

The sides \( AB \), \( BC \), and \( CA \) of a triangle \( \triangle ABC \) have respectively 3, 4, and 5 points lying on them. The number of triangles that can be constructed using these points as vertices is

  • (1) 205
  • (2) 220
  • (3) 210
  • (4) None of these

Question 112:

In the expansion of \( a + bx \), the coefficient of \( x^r \) is

  • (1) \( a - br \)
  • (2) \( a + br \)
  • (3) \( (1 - r) a - br \)
  • (4) None of these

Question 113:

If \( n = 1999 \), then \( \sum_{i=1}^{1999} \log x_i \) is equal to

  • (1) \( \log 1999 \)
  • (2) 0
  • (3) \( -1 \)
  • (4) \( \log 1999! \)

Question 114:

\( P \) is a fixed point \( (a, a, a) \) on a line through the origin equally inclined to the axes, then any plane through \( P \) perpendicular to \( OP \), makes intercepts on the axes, the sum of whose reciprocals is equal to

  • (1) \( \frac{3a}{2} \)
  • (2) \( \frac{a}{2} \)
  • (3) \( 2a \)
  • (4) None of these

Question 115:

For which of the following values of \( m \), the area of the region bounded by the curve \( y = x - x^2 \) and the line \( y = mx \) equals 5?

  • (1) \( -4 \)
  • (2) \( -2 \)
  • (3) \( 2 \)
  • (4) \( 4 \)

Question 116:

If \( R \to R \) be such that \( f(1) = 3 \) and \( f'(1) = 6 \), then \( f(x) \) is equal to

  • (1) \( e^x \)
  • (2) \( e^{x^2} \)
  • (3) \( e^{3x} \)
  • (4) \( e^{x^3} \)

Question 117:

If \( f(x) = \left\{ \begin{array}{ll} 1 + \left| \sin x \right|, & for -\pi \leq x < 0
e^{x/2}, & for 0 \leq x < \pi
\end{array} \right. \)

then the value of \( a \) and \( b \), if \( f \) is continuous at \( x = 0 \), are respectively

  • (1) \( a = 3, b = e^3 \)
  • (2) \( a = 2, b = e^3 \)
  • (3) \( a = 3, b = 2 \)
  • (4) \( a = 1, b = 2 \)

Question 118:

The domain of the function
\[ f(x) = \frac{1}{\log(1 - x)} + \sqrt{x + 2} \]

is

  • (1) \( [-3, -2] \cup [0, \infty) \)
  • (2) \( [-3, 2] \)
  • (3) \( [0, \infty) \)
  • (4) \( [-3, -2] \cup [2, \infty) \)

Question 119:

The solution of the differential equation
\[ (1 + y^2) \, \frac{dy}{dx} = e^{-(x - y)} \]

is

  • (1) \( (x - 2) = K \cdot e^{-1} y \)
  • (2) \( x \cdot e^{2y} = e^y + K \)
  • (3) \( x \cdot e^{2y} = e^{-1} y + K \)
  • (4) \( x \cdot e^{1} y = e^{y} + K \)

Question 120:

If the gradient of the tangent at any point \( (x, y) \) of a curve passing through the point \( (1, \frac{\pi}{4}) \) is
\[ \left| \frac{dy}{dx} \right| = \frac{1}{x} \cdot \left| \log \left( \frac{y}{x} \right) \right| \]

then the equation of the curve is

  • (1) \( y = \cot(\log x) \)
  • (2) \( y = \cot(\log x) \)
  • (3) \( y = \cot(\log x) \)
  • (4) \( y = \cot(\log x) \)