NCERT Solutions For Class 12 Chemistry Chapter 4: Chemical Kinetics

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NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics deals with the study of the rate of reaction and variables that affect chemical reactions. Some of the important topics covered in this chapter are as follows:

  1. Integrated Rate Equations
  2. Rate of a Chemical Reaction
  3. Electrophoresis
  4. Collision Theory
  5. Order of Reaction
  6. Pseudo First Order Reaction
  7. Rate of Reaction
  8. First Order Reaction
  9. Half-Life

Expected no. of questions: 2 to 4 questions of 7 marks.

Download PDF: NCERT Solutions for Class 12 Chemistry Chapter 4 pdf


NCERT Solutions for Class 12 Chemistry Chapter 4

The NCERT Solutions for Class 12 Chemistry Chapter 4 Chemical Kinetics is as given below.

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Class 12 Chemistry Chapter 4 Chemical Kinetics – Important Topics

Chemical kinetics deals with the rate of chemical reactions. A chemical reaction is a process in which one or more reactants are converted to one or more products. Rate of reaction is the rate at which the concentration of either reactants or products gets increased or decreased.

Rate = K[A]x [B]y

Arrhenius equation established the relation between temperature and rate constant.

Arrhenius Equation k = Ae -Ea/RT

Half life of a reaction is the time taken by the reactants to reduce its concentration to half compared to its initial concentration.

Half Life T½  = 0.693/k

Order of Reaction is the sum of powers of the exponent in the rate equation. There are 3 orders of reaction, namely,

  • Zero order reaction
  • First order reaction
  • Second order reaction
  • Pseudo first order reaction

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CBSE CLASS XII Related Questions

  • 1.
    For a reaction : \( N_2 + 3H_2 \rightarrow 2NH_3 \), the rate of reaction with respect to \( NH_3 \) is

      • \( +\frac{1}{3} \frac{\Delta [NH_3]}{\Delta t} \)
      • \( -\frac{1}{2} \frac{\Delta [NH_3]}{\Delta t} \)
      • \( +\frac{1}{4} \frac{\Delta [NH_3]}{\Delta t} \)
      • \( +\frac{1}{2} \frac{\Delta [NH_3]}{\Delta t} \)

    • 2.
      Consider the following reaction and identify A and B: \[ CH_3Cl + NaI \xrightarrow{\text{dry acetone}} A + B \]

        • A = CH\(_3\)I, B = NaCl
        • A = CH\(_3\)OH, B = NaCl
        • A = CH\(_3\)CHO, B = NaCl
        • A = C\(_2\)H\(_6\), B = CH\(_3\)I

      • 3.
        What happens when acidic solution of potassium permanganate is allowed to stand for sometime ? Give the equation involved. What is this type of reaction called ?


          • 4.
            Which of the following Grignard Reagent will be used to prepare cyclohexylmethanol when treated with methanal?

              • A
              • B
              • C
              • D

            • 5.
              Half-life (\( t_{1/2} \)) of a first order reaction is 1386 s. The value of rate constant is:

                • \(0.5 \times 10^{-4} \, \text{s}^{-1}\)
                • \(5.0 \times 10^{-4} \, \text{s}^{-1}\)
                • \(0.5 \times 10^{-5} \, \text{s}^{-1}\)
                • \(0.5 \times 10^{-3} \, \text{s}^{-1}\)

              • 6.
                Name the cell which was used in the Apollo space programme for providing electrical power.

                  CBSE CLASS XII Previous Year Papers

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