Atomic Structure carries approximately 2-3% weightage under the JEE Advanced 2025 exam according to the new JEE Advanced 2025 syllabus and previous years trends. The subject is considered moderately difficult as per conceptual depth. Common concepts such as Bohr’s Model, Quantum Numbers, Electronic Configuration, and Atomic Spectra are repeatedly asked in JEE Advanced previous year question papers. Hence, revising these core concepts is highly recommended for good exam performance.

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Most important Topics for JEE Advanced 2025 (Atomic Structure):

Based on the JEE Advanced previous year paper trends, the following are the high-weightage topics in JEE Advanced 2025:

  • Quantum Numbers and Orbitals (JEE Advanced 2018, Paper 2)
  • Bohr’s Model and Energy Levels (JEE Advanced 2016, Paper 1)
  • Atomic Spectra and Hydrogen Spectrum (JEE Advanced 2019, Paper 1)
  • Electronic Configuration and Aufbau Principle (JEE Advanced 2017, Paper 2)
  • de Broglie Hypothesis and Wave-Particle Duality (JEE Advanced 2021, Paper 1)
  • Heisenberg’s Uncertainty Principle (JEE Advanced 2015, Paper 1)

JEE Advanced previous year question papers and mock tests can assist IIT Aspirants to achieve higher rankings in JEE Advanced 2025.

Listed below the most repeated questions JEE Advanced Previous Year Questions (PYQs) for Atomic Structure along with detailed solutions
 

1. The radius corresponding to 3 → 2 transition of hydrogen atom falls on a metal surface to produce photoelectrons. These electrons are made to enter a magnetic field of 3 × 10-4 T. If the radius of the largest circular path followed by these electrons is 10.0 mm, the work function of the metal is close to
JEE Advanced 2014 JEE Advanced
A 1.8 eV
B 1.1 eV
C 0.8 eV
D 1.6 eV
2. The kinetic energy of an electron in the second Bohr orbit of a hydrogen atom is [a0 is Bohr radius]
JEE Advanced 2012 JEE Advanced
A h2/4π2ma02
B h2/16π2ma02
C h2/32π2ma02
D h2/64π2ma02
3. The reagent(s) used for softening the temporary hardness of water is(are)
JEE Advanced 2010 JEE Advanced
A Ca3(PO4)2
B Ca(OH)2
C Na2CO3
D NaOCl
4. Principal quantum number of an atom is related to the
JEE Advanced 1983 JEE Advanced
A orbital angular momentum
B spin angular momentum
C size of the orbital
D orientation of the orbital in space
5. The colour of the X2 molecules of group 17 elements changes gradually from yellow to violet down the group. This is due to
JEE Advanced 2017 JEE Advanced
A the physical state of X2 at room temperature changes from gas to solid down the group
B decrease in ionization energy down the group
C decrease in π* - σ* gap down the group
D decrease in HOMO-LUMO gap down the group

JEE Advanced 2025 Chapter-Wise Weightage For Chemistry

Chapter Name Approx. Weightage (%) No. of Expected Questions
Chemical Thermodynamics 6–8% 2
Atomic Structure 5% 1–2
Chemical Bonding & Molecular Structure 6–7% 2
Equilibrium (Ionic + Chemical) 7–9% 2–3
Electrochemistry 5–6% 1–2
Solutions & Colligative Properties 4–5% 1–2
Redox Reactions 3% 1
Surface Chemistry 3% 1
Solid State 3–4% 1
Kinetics 5–6% 1–2
Organic Chemistry (General + Named Reactions) 12–14% 4–5
Biomolecules, Polymers, Chemistry in Everyday Life 4–5% 1–2
Coordination Compounds 6–7% 2
The d- and f-Block Elements 5% 1–2
Qualitative Inorganic Analysis 4% 1

JEE Advanced 2025 Difficulty Analysis For Chemistry

Chapter Name Difficulty Level (Easy / Moderate / Hard)
Chemical Thermodynamics Moderate to Hard
Atomic Structure Moderate
Chemical Bonding Moderate
Equilibrium Hard
Electrochemistry Hard
Solutions Moderate
Redox Reactions Easy
Surface Chemistry Easy
Solid State Moderate
Chemical Kinetics Moderate
Organic Chemistry (Full) Moderate to Hard
Biomolecules & Polymers Easy
Coordination Compounds Hard
d- and f-Block Elements Moderate
Inorganic Qualitative Analysis Hard

Download Last 10 years JEE Advanced Previous Year Question Papers (2024 - 2016)

IIIT JEE Advanced Previous Year Question Papers

You can download free IIT JEE Advanced Previous Year Question Paper PDFs from the table provided below:-

JEE Advanced Paper Name Question Paper Link
JEE Advanced 2024 Question Paper PDF Click Here
JEE Advanced 2023 Question Paper PDF Click Here
JEE Advanced 2022 Question Paper PDF Click Here
JEE Advanced 2021 Question Paper PDF Click Here
JEE Advanced 2020 Question Paper PDF Click Here
JEE Advanced 2019 Question Paper PDF Click Here
JEE Advanced 2018 Question Paper PDF Click Here
JEE Advanced 2017 Question Paper PDF Click Here
JEE Advanced 2016 Question Paper PDF Click Here

Frequently Asked Questions:-

1. How many questions come from Atomic Structure in JEE Advanced?

In JEE Advanced, you can anticipate 2 to 3 questions from Atomic Structure every year. It's not the largest topic, but it appears frequently. Sometimes it combines with other topics such as Quantum Mechanics or Periodic Table, so the number may vary a bit. Nevertheless, it's a significant part of Chemistry, so it's definitely worth studying!

2. Is Atomic Structure hard for JEE?

It varies depending on how well you get it. Atomic Structure is not the most difficult subject, but it's not very easy either. It has some confusing concepts, such as Bohr's model, quantum numbers, and spectral lines, which can be confusing initially. But if you understand the fundamentals well—such as protons, electrons, and orbits—it becomes easier. Try solving some numerical problems, and you'll be fine. For most students, it's not as difficult as Organic Chemistry!

3. Is IIT Advanced tough?

Yes, IIT Advanced is extremely difficult! It's much more difficult than JEE Main. The questions probe your knowledge, problem-solving skills, and quick thinking. It's not merely memorizing—it's applying what you know in intelligent ways. But with proper preparation and practice, one can score a good score!

4. What are the essential questions for Atomic Structure?

Following are the important topics and questions you must address for Atomic Structure:

Bohr’s Model: Calculate the energy or radius of an electron in a specific orbit.

Quantum Numbers: Discover how many electrons possess particular n, l, or m values.

Spectral Lines: the frequency or wavelength when an electron transitions from one orbit to another (e.g., Balmer or Lyman series).

De Broglie Wavelength: Discover wavelength of a traveling particle given its mass and speed.

Ionization Energy: What amount of energy is required to take away an electron from an atom such as hydrogen or helium ion.