JEE Main 2026 Jan 21 Shift 2 question paper is available here with answer key and solutions. NTA conducted the JEE Main shift 2 from 3 PM to 6 PM.

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Based on initial analysis, JEE Main Jan 21 Shift 2 was Easy to Moderate, where Mathematics remained the lengthiest section. Students can access the JEE Main today paper shift 2 pdf with answer keys here.

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JEE Mains 2026 21 Jan Shift 2 Question Paper with Solutions

Question 1:

Let \(A = \{2, 3, 5, 7, 9\}\). Let \(R\) be the relation on \(A\) defined by \(xRy\) if and only if \(2x \le 3y\). Let \(l\) be the number of elements in \(R\), and \(m\) be the minimum number of elements required to be added in \(R\) to make it a symmetric relation. Then \(l + m\) is equal to :

  • (A) 23
  • (B) 21
  • (C) 25
  • (D) 27

Question 2:

Let \(z\) be the complex number satisfying \(|z - 5| \le 3\) and having maximum positive principal argument. Then \(34 \left| \frac{5z - 12}{5iz + 16} \right|^2\) is equal to :

  • (A) 12
  • (B) 16
  • (C) 26
  • (D) 20

Question 3:

Let \(\alpha\) and \(\beta\) be the roots of the equation \(x^2 + 2ax + (3a + 10) = 0\) such that \(\alpha < 1 < \beta\). Then the set of all possible values of \(a\) is :

  • (A) \((-\infty, -\frac{11}{5}) \cup (5, \infty)\)
  • (B) \((-\infty, -3)\)
  • (C) \((-\infty, -2) \cup (5, \infty)\)
  • (D) \((-\infty, -\frac{11}{5})\)

Question 4:

If the line \(ax + 4y = \sqrt{7}\), where \(a \in \mathbb{R}\), touches the ellipse \(3x^2 + 4y^2 = 1\) at the point \(P\) in the first quadrant, then one of the focal distances of \(P\) is :

  • (A) \(\frac{1}{\sqrt{3}} + \frac{1}{2\sqrt{5}}\)
  • (B) \(\frac{1}{\sqrt{3}} + \frac{1}{2\sqrt{7}}\)
  • (C) \(\frac{1}{\sqrt{3}} - \frac{1}{2\sqrt{5}}\)
  • (D) \(\frac{1}{\sqrt{3}} - \frac{1}{2\sqrt{11}}\)

Question 5:

Let \(A = \{x : |x^2 - 10| \le 6\}\) and \(B = \{x : |x - 2| > 1\}\). Then

  • (A) \(A - B = [2, 3]\)
  • (B) \(A \cap B = [-4, -2] \cup [3, 4]\)
  • (C) \(B - A = (-\infty, -4) \cup (-2, 1) \cup (4, \infty)\)
  • (D) \(A \cup B = (-\infty, 1] \cup (2, \infty)\)

Question 6:

Let \(f(x) = x^3 + x^2 f'(1) + 2x f''(2) + f'''(3), x \in \mathbb{R}\). Then the value of \(f'(5)\) is :

  • (A) \(\frac{62}{5}\)
  • (B) \(\frac{657}{5}\)
  • (C) \(\frac{215}{5}\)
  • (D) \(\frac{117}{5}\)

Question 7:

Let the line \(L_1\) be parallel to the vector \(-3\hat{i} + 2\hat{j} + 4\hat{k}\) and pass through the point \((2, 6, 7)\), and the line \(L_2\) be parallel to the vector \(2\hat{i} + \hat{j} + 3\hat{k}\) and pass through the point \((4, 3, 5)\). If the line \(L_3\) is parallel to the vector \(-3\hat{i} + 5\hat{j} + 16\hat{k}\) and intersects the lines \(L_1\) and \(L_2\) at the points \(C\) and \(D\), respectively, then \(|\vec{CD}|^2\) is equal to :

  • (A) 290
  • (B) 89
  • (C) 312
  • (D) 171

Question 8:

Let \(y = y(x)\) be the solution of the differential equation \(\sec x \frac{dy}{dx} - 2y = 2 + 3\sin x, x \in (-\frac{\pi}{2}, \frac{\pi}{2})\). If \(y(0) = -\frac{7}{4}\), then \(y(\frac{\pi}{6})\) is equal to :

  • (A) \(-\frac{5}{2}\)
  • (B) \(-\frac{5}{4}\)
  • (C) \(-3\sqrt{2} - 7\)
  • (D) \(-3\sqrt{3} - 7\)

Question 9:

If the area of the region \(\{(x, y) : 1 - 2x \le y \le 4 - x^2, x \ge 0, y \ge 0\}\) is \(\frac{\alpha}{\beta}\), \(\alpha, \beta \in \mathbb{N}\), \(\gcd(\alpha, \beta) = 1\), then the value of \((\alpha + \beta)\) is :

  • (A) 67
  • (B) 85
  • (C) 91
  • (D) 73

Question 10:

Let \(a_1, \frac{a_2}{2}, \frac{a_3}{2^2}, \dots, \frac{a_{10}}{2^9}\) be a G.P. of common ratio \(\frac{1}{\sqrt{2}}\). If \(a_1 + a_2 + \dots + a_{10} = 62\), then \(a_1\) is equal to :

  • (A) \(2 - \sqrt{2}\)
  • (B) \(2(2 - \sqrt{2})\)
  • (C) \(\sqrt{2} - 1\)
  • (D) \(2(\sqrt{2} - 1)\)

Question 11:

Let \( f: \mathbb{R} \to \mathbb{R} \) be a twice differentiable function such that \( f''(x) > 0 \) for all \( x \in \mathbb{R} \) and \( f'(a-1) = 0 \), where \( a \) is a real number. Let \( g(x) = f(\tan^2 x - 2\tan x + a) \), \( 0 < x < \frac{\pi}{2} \).

Consider the following two statements :

(I) \( g \) is increasing in \( (0, \frac{\pi}{4}) \)

(II) \( g \) is decreasing in \( (\frac{\pi}{4}, \frac{\pi}{2}) \)

Then,

  • (A) Only (II) is True
  • (B) Only (I) is True
  • (C) Both (I) and (II) are True
  • (D) Neither (I) nor (II) is True

Question 12:

For the matrices \( A = \begin{bmatrix} 3 & -4
1 & -1 \end{bmatrix} \) and \( B = \begin{bmatrix} -29 & 49
-13 & 18 \end{bmatrix} \), if \( (A^{15} + B) \begin{bmatrix} x
y \end{bmatrix} = \begin{bmatrix} 0
0 \end{bmatrix} \), then among the following which one is true?

  • (A) \( x = 16, y = 3 \)
  • (B) \( x = 18, y = 11 \)
  • (C) \( x = 5, y = 7 \)
  • (D) \( x = 11, y = 2 \)

Question 13:

Let one end of a focal chord of the parabola \( y^2 = 16x \) be \( (16, 16) \). If \( P(\alpha, \beta) \) divides this focal chord internally in the ratio \( 5 : 2 \), then the minimum value of \( \alpha + \beta \) is equal to :

  • (A) 5
  • (B) 7
  • (C) 16
  • (D) 22

Question 14:

Let \( y^2 = 12x \) be the parabola with its vertex at \( O \). Let \( P \) be a point on the parabola and \( A \) be a point on the \( x \)-axis such that \( \angle OPA = 90^\circ \). Then the locus of the centroid of such triangles \( OPA \) is :

  • (A) \( y^2 - 4x + 8 = 0 \)
  • (B) \( y^2 - 6x + 4 = 0 \)
  • (C) \( y^2 - 9x + 6 = 0 \)
  • (D) \( y^2 - 2x + 8 = 0 \)

Question 15:

The positive integer \( n \), for which the solutions of the equation \( x(x+2) + (x+2)(x+4) + \dots + (x+2n-2)(x+2n) = \frac{8n}{3} \) are two consecutive even integers, is :

  • (A) 9
  • (B) 3
  • (C) 12
  • (D) 6

Question 16:

A random variable \( X \) takes values \( 0, 1, 2, 3 \) with probabilities \( \frac{2a+1}{30}, \frac{8a-1}{30}, \frac{4a+1}{30}, b \) respectively, where \( a, b \in \mathbb{R} \). Let \( \mu \) and \( \sigma \) respectively be the mean and standard deviation of \( X \) such that \( \sigma^2 + \mu^2 = 2 \). Then \( \frac{a}{b} \) is equal to :

  • (A) 12
  • (B) 3
  • (C) 60
  • (D) 30

Question 17:

Let the line \( L \) pass through the point \( (-3, 5, 2) \) and make equal angles with the positive coordinate axes. If the distance of \( L \) from the point \( (-2, r, 1) \) is \( \sqrt{\frac{14}{3}} \), then the sum of all possible values of \( r \) is :

  • (A) 16
  • (B) 12
  • (C) 10
  • (D) 6

Question 18:

The largest \( n \in \mathbb{N} \), for which \( 7^n \) divides \( 101! \), is :

  • (A) 15
  • (B) 19
  • (C) 16
  • (D) 18

Question 19:

For a triangle \( ABC \), let \( \vec{p} = \vec{BC} \), \( \vec{q} = \vec{CA} \) and \( \vec{r} = \vec{BA} \). If \( |\vec{p}| = 2\sqrt{3}, |\vec{q}| = 2 \) and \( \cos \theta = -\frac{1}{\sqrt{3}} \), where \( \theta \) is the angle between \( \vec{p} \) and \( \vec{q} \), then \( |\vec{p} \times (\vec{q} - 3\vec{r})|^2 + 3|\vec{r}|^2 \) is equal to :

  • (A) 340
  • (B) 220
  • (C) 200
  • (D) 410

Question 20:

If the system of equations
\( 3x + y + 4z = 3 \)
\( 2x + \alpha y - z = -3 \)
\( x + 2y + z = 4 \)

has no solution, then the value of \( \alpha \) is equal to :

  • (A) 19
  • (B) 13
  • (C) 4
  • (D) 23

Question 21:

Let the maximum value of \( (\sin^{-1}x)^2 + (\cos^{-1}x)^2 \) for \( x \in \left[ -\frac{\sqrt{3}}{2}, \frac{1}{\sqrt{2}} \right] \) be \( \frac{m}{n}\pi^2 \), where \( \gcd(m, n) = 1 \). Then \( m + n \) is equal to ___________.


Question 22:

If \( \left( \frac{1}{{}^{15}C_0} + \frac{1}{{}^{15}C_1} \right) \left( \frac{1}{{}^{15}C_1} + \frac{1}{{}^{15}C_2} \right) \dots \left( \frac{1}{{}^{15}C_{12}} + \frac{1}{{}^{15}C_{13}} \right) = \frac{\alpha^{13}}{{}^{14}C_0 {}^{14}C_1 \dots {}^{14}C_{12}} \), then \( 30\alpha \) is equal to ___________.


Question 23:

Let \( [ \cdot ] \) denote the greatest integer function and \( f(x) = \lim_{n \to \infty} \frac{1}{n^3} \sum_{k=1}^{n} \left[ \frac{k^2}{3^x} \right] \). Then \( 12 \sum_{j=1}^{\infty} f(j) \) is equal to ___________.


Question 24:

If \( P \) is a point on the circle \( x^2 + y^2 = 4 \), \( Q \) is a point on the straight line \( 5x + y + 2 = 0 \) and \( x - y + 1 = 0 \) is the perpendicular bisector of \( PQ \), then 13 times the sum of abscissa of all such points \( P \) is ___________.


Question 25:

If \( \int_0^1 4 \cot^{-1}(1 - 2x + 4x^2) dx = a \tan^{-1}(2) - b \ln(5) \), where \( a, b \in \mathbb{N} \), then \( (2a + b) \) is equal to ___________.


Question 26:

Consider two identical metallic spheres of radius \(R\) each having charge \(Q\) and mass \(m\). Their centers have an initial separation of \(4R\). Both the spheres are given an initial speed of \(u\) towards each other. The minimum value of \(u\), so that they can just touch each other is :
(Take \(k = \frac{1}{4 \pi \epsilon_0}\) and assume \(kQ^2 > Gm^2\) where \(G\) is the Gravitational constant)

  • (A) \(\sqrt{\frac{kQ^2}{4mR} \left( 1 - \frac{Gm^2}{kQ^2} \right)}\)
  • (B) \(\sqrt{\frac{kQ^2}{2mR} \left( 1 - \frac{Gm^2}{kQ^2} \right)}\)
  • (C) \(\sqrt{\frac{kQ^2}{2mR} \left( 1 - \frac{Gm^2}{2kQ^2} \right)}\)
  • (D) \(\sqrt{\frac{kQ^2}{4mR} \left( 1 + \frac{Gm^2}{kQ^2} \right)}\)

Question 27:

Surface tension of two liquids (having same densities), \(T_1\) and \(T_2\) are measured using capillary rise method utilizing two tubes with inner radii of \(r_1\) and \(r_2\) where \(r_1 > r_2\). The measured liquid heights in these tubes are \(h_1\) and \(h_2\) respectively. [Ignore the weight of the liquid about the lowest point of meniscus]. The heights \(h_1\) and \(h_2\) and surface tensions \(T_1\) and \(T_2\) satisfy the relation :

  • (A) \(h_1 > h_2\) and \(T_1 < T_2\)
  • (B) \(h_1 = h_2\) and \(T_1 = T_2\)
  • (C) \(h_1 < h_2\) and \(T_1 = T_2\)
  • (D) \(h_1 > h_2\) and \(T_1 = T_2\)

Question 28:

The total length of potentiometer wire AB is \(50\) cm in the arrangement as shown in figure. If P is the point where the galvanometer shows zero reading then the length AP is ___________ cm.


  • (A) 30
  • (B) 25
  • (C) 15
  • (D) 20

Question 29:

Keeping the significant figures in view, the sum of the physical quantities \(52.01\) m, \(153.2\) m and \(0.123\) m is :

  • (A) \(205.33\) m
  • (B) \(205.333\) m
  • (C) \(205\) m
  • (D) \(205.3\) m

Question 30:

Two cars \(A\) and \(B\) each of mass \(10^3\) kg are moving on parallel tracks separated by a distance of \(10\) m, in same direction with speeds \(72\) km/h and \(36\) km/h. The magnitude of angular momentum of car \(A\) with respect to car \(B\) is ___________ J.s.

  • (A) \(3 \times 10^5\)
  • (B) \(10^5\)
  • (C) \(3.6 \times 10^5\)
  • (D) \(2 \times 10^5\)

Question 31:

Two known resistances of \(R \Omega\) and \(2R \Omega\) and one unknown resistance \(X \Omega\) are connected in a circuit as shown in the figure. If the equivalent resistance between points \(A\) and \(B\) in the circuit is \(X \Omega\), then the value of \(X\) is ___________ \(\Omega\).


  • (A) \(R\)
  • (B) \((\sqrt{3} - 1)R\)
  • (C) \(2(\sqrt{3} - 1)R\)
  • (D) \((\sqrt{3} + 1)R\)

Question 32:

An infinitely long straight wire carrying current \(I\) is bent in a planar shape as shown in the diagram. The radius of the circular part is \(r\). The magnetic field at the centre \(O\) of the circular loop is :


  • (A) \(\frac{\mu_0 I}{2 \pi r} (\pi - 1) \hat{i}\)
  • (B) \(\frac{\mu_0 I}{2 \pi r} (\pi + 1) \hat{i}\)
  • (C) \(-\frac{\mu_0 I}{2 \pi r} (\pi - 1) \hat{i}\)
  • (D) \(-\frac{\mu_0 I}{2 \pi r} (\pi + 1) \hat{i}\)

Question 33:

The energy of an electron in an orbit of the Bohr's atom is \(-0.04 E_g\) where \(E_g\) is the ground state energy. If \(L\) is the angular momentum of the electron in this orbit and \(h\) is the Planck's constant, then \(\frac{2 \pi L}{h}\) is ___________ :

  • (A) 4
  • (B) 6
  • (C) 5
  • (D) 2

Question 34:

As shown in the diagram, when the incident ray is parallel to base of the prism, the emergent ray grazes along the second surface. If refractive index of the material of prism is \(\sqrt{2}\), the angle \(\theta\) of prism is :


  • (A) \(90^\circ\)
  • (B) \(45^\circ\)
  • (C) \(75^\circ\)
  • (D) \(60^\circ\)

Question 35:

Given below are two statements :

Statement I : In a Young's double slit experiment, the angular separation of fringes will increase as the screen is moved away from the plane of the slits

Statement II : In a Young's double slit experiment, the angular separation of fringes will increase when monochromatic source is replaced by another monochromatic source of higher wavelength

In the light of the above statements, choose the correct answer from the options given below :

  • (A) Both Statement I and Statement II are true
  • (B) Both Statement I and Statement II are false
  • (C) Statement I is true but Statement II is false
  • (D) Statement I is false but Statement II is true

Question 36:

The kinetic energy of a simple harmonic oscillator is oscillating with angular frequency of 176 rad/s. The frequency of this simple harmonic oscillator is \hspace{1cm} Hz. [Take \(\pi = \frac{22}{7}\)]

  • (A) 28
  • (B) 176
  • (C) 14
  • (D) 88

Question 37:

A body of mass 2 kg is moving along x-direction such that its displacement as function of time is given by \(x(t) = \alpha t^2 + \beta t + \gamma\) m, where \(\alpha = 1\) m/s\(^2\), \(\beta = 1\) m/s and \(\gamma = 1\) m. The work done on the body during the time interval \(t = 2\) s to \(t = 3\) s, is ___________ J.

  • (A) 42
  • (B) 24
  • (C) 12
  • (D) 49

Question 38:

A large drum having radius \(R\) is spinning around its axis with angular velocity \(\omega\), as shown in figure. The minimum value of \(\omega\) so that a body of mass \(M\) remains stuck to the inner wall of the drum, taking the coefficient of friction between the drum surface and mass \(M\) as \(\mu\), is :


  • (A) \(\sqrt{\frac{\mu g}{R}}\)
  • (B) \(\sqrt{\frac{g}{\mu R}}\)
  • (C) \(\sqrt{\frac{2g}{\mu R}}\)
  • (D) \(\sqrt{\frac{g}{2\mu R}}\)

Question 39:

A capacitor \(C\) is first charged fully with potential difference of \(V_0\) and disconnected from the battery. The charged capacitor is connected across an inductor having inductance \(L\). In \(t\) s 25% of the initial energy in the capacitor is transferred to the inductor. The value of \(t\) is ___________ s.

  • (A) \(\pi \sqrt{\frac{LC}{2}}\)
  • (B) \(\frac{\pi \sqrt{LC}}{6}\)
  • (C) \(\frac{\pi \sqrt{LC}}{3}\)
  • (D) \(\frac{\pi \sqrt{LC}}{2}\)

Question 40:

A spherical body of radius \(r\) and density \(\sigma\) falls freely through a viscous liquid having density \(\rho\) and viscosity \(\eta\) and attains a terminal velocity \(v_0\). Estimated maximum error in the quantity \(\eta\) is : (Ignore errors associated with \(\sigma\), \(\rho\) and \(g\), gravitational acceleration)

  • (A) \(2 \left[ \frac{\Delta r}{r} - \frac{\Delta v_0}{v_0} \right]\)
  • (B) \(2 \left[ \frac{\Delta r}{r} + \frac{\Delta v_0}{v_0} \right]\)
  • (C) \(\frac{2 \Delta r}{r} + \frac{\Delta v_0}{v_0}\)
  • (D) \(2 \frac{\Delta r}{r} - \frac{\Delta v_0}{v_0}\)

Question 41:

A river of width 200 m is flowing from west to east with a speed of 18 km/h. A boat, moving with speed of 36 km/h in still water, is made to travel one-round trip (bank to bank of the river). Minimum time taken by the boat for this journey and also the displacement along the river bank are \hspace{1cm} and \hspace{1cm} respectively.

  • (A) 20 s and 100 m
  • (B) 40 s and 100 m
  • (C) 40 s and 0 m
  • (D) 40 s and 200 m

Question 42:

The r.m.s. speed of oxygen molecules at 47 \(^\circ\)C is equal to that of the hydrogen molecules kept at ___________ \(^\circ\)C. (Mass of oxygen molecule/mass of hydrogen molecule = 32/2)

  • (A) \(-20\)
  • (B) \(-253\)
  • (C) \(-235\)
  • (D) \(-100\)

Question 43:

The charge stored by the capacitor C in the given circuit in the steady state is \hspace{1cm} \(\mu\)C.


  • (A) 10
  • (B) 7.5
  • (C) 5
  • (D) 12.5

Question 44:

A battery with EMF \(E\) and internal resistance \(r\) is connected across a resistance \(R\). The power consumption in \(R\) will be maximum when :

  • (A) \(R = r\)
  • (B) \(R = r/2\)
  • (C) \(R = \sqrt{2} r\)
  • (D) \(R = 2r\)

Question 45:

The pulley shown in figure is made using a thin rim and two rods of length equal to diameter of the rim. The rim and each rod have a mass of \(M\). Two blocks of mass of \(M\) and \(m\) are attached to two ends of a light string passing over the pulley, which is hinged to rotate freely in vertical plane about its center. The magnitudes of the acceleration experienced by the blocks is ___________ (assume no slipping of string on pulley).


  • (A) \(\frac{(M-m)g}{\left(\frac{13}{6}\right)M + m}\)
  • (B) \(\frac{(M-m)g}{\left(\frac{8}{3}\right)M + m}\)
  • (C) \(\frac{(M-m)g}{2M + m}\)
  • (D) \(\frac{(M-m)g}{M + m}\)

Question 46:

An electromagnetic wave of frequency 100 MHz propagates through a medium of conductivity, \(\sigma = 10\) mho/m. The ratio of maximum conduction current density to maximum displacement current density is \hspace{1cm.
\(\left[ Take \frac{1{4\pi\epsilon_0} = 9 \times 10^9 Nm^2/C^2 \right]\)


Question 47:

A diatomic gas (\(\gamma = 1.4\)) does 100 J of work when it is expanded isobarically. Then the heat given to the gas is ___________ J.


Question 48:

In a Young's double slit experiment set up, the two slits are kept 0.4 mm apart and screen is placed at 1 m from slits. If a thin transparent sheet of thickness 20 \(\mu\)m is introduced in front of one of the slits then center bright fringe shifts by 20 mm on the screen. The refractive index of transparent sheet is given by \(\frac{\alpha}{10}\), where \(\alpha\) is ___________.


Question 49:

A particle having electric charge \(3 \times 10^{-19}\) C and mass \(6 \times 10^{-27}\) kg is accelerated by applying an electric potential of 1.21 V. Wavelength of the matter wave associated with the particle is \(\alpha \times 10^{-12}\) m. The value of \(\alpha\) is \hspace{1cm. (Take Planck's constant \(= 6.6 \times 10^{-34\) J.s)


Question 50:

The terminal velocity of a metallic ball of radius 6 mm in a viscous fluid is 20 cm/s. The terminal velocity of another ball of same material and having radius 3 mm in the same fluid will be \hspace{1cm} cm/s.


Question 51:

For a closed circuit Daniell cell, which of the following plots is the accurate one at a given temperature ?

  • (A)
  • (B)
  • (C)
  • (D)

Question 52:

Given below are four compounds :

(a) n-propyl chloride

(b) iso-propyl chloride

(c) sec-butyl chloride

(d) neo-pentyl chloride

Percentage of carbon in the one which exhibits optical isomerism is :

  • (A) 56
  • (B) 40
  • (C) 46
  • (D) 52

Question 53:

Given below are two statements :

Statement I : Crystal Field Stabilization Energy (CFSE) of \( [Cr(H_2O)_6]^{2+} \) is greater than that of \( [Mn(H_2O)_6]^{2+} \).

Statement II : Potassium ferricyanide has a greater spin-only magnetic moment than sodium ferrocyanide.

In the light of the above statements, choose the correct answer from the options given below :

  • (A) Statement I is true but Statement II is false
  • (B) Statement I is false but Statement II is true
  • (C) Both Statement I and Statement II are true
  • (D) Both Statement I and Statement II are false

Question 54:

The correct statements are :

A. Activation energy for enzyme catalysed hydrolysis of sucrose is lower than that of acid catalysed hydrolysis.

B. During denaturation, secondary and tertiary structures of a protein are destroyed but primary structure remains intact.

C. Nucleotides are joined together by glycosidic linkage between \( C_1 \) and \( C_4 \) carbons of the pentose sugar.

D. Quaternary structure of proteins represents overall folding of the polypeptide chain.

Choose the correct answer from the options given below :

  • (A) A, B and D Only
  • (B) A and B Only
  • (C) B and C Only
  • (D) A, C and D Only

Question 55:

By usual analysis, 1.00 g of compound (X) gave 1.79 g of magnesium pyrophosphate. The percentage of phosphorus in compound (X) is : \hspace{1cm} (nearest integer)
(Given, molar mass in g mol\(^{-1}\) ; O = 16, Mg = 24, P = 31)

  • (A) 20
  • (B) 40
  • (C) 30
  • (D) 50

Question 56:

Aqueous HCl reacts with \( MnO_2(s) \) to form \( MnCl_2(aq) \), \( Cl_2(g) \) and \( H_2O(l) \). What is the weight (in g) of \( Cl_2 \) liberated when 8.7 g of \( MnO_2(s) \) is reacted with excess aqueous HCl solution ?
(Given Molar mass in g mol\(^{-1}\) : Mn = 55, Cl = 35.5, O = 16, H = 1)

  • (A) 21.3
  • (B) 71
  • (C) 14.2
  • (D) 7.1

Question 57:

Match List - I with List - II.



Choose the correct answer from the options given below :

  • (A) A-II, B-III, C-IV, D-I
  • (B) A-II, B-IV, C-I, D-III
  • (C) A-IV, B-I, C-II, D-III
  • (D) A-IV, B-III, C-I, D-II

Question 58:

Given below are two statements :

Statement I : The correct order in terms of bond dissociation enthalpy is \( Cl_2 > Br_2 > F_2 > I_2 \).

Statement II : The correct trend in the covalent character of the metal halides is \( SnCl_2 > SnCl_4 \), \( PbCl_2 > PbCl_4 \) and \( UF_4 > UF_6 \).

In the light of the above statements, choose the correct answer from the options given below :

  • (A) Both Statement I and Statement II are true
  • (B) Statement I is false but Statement II is true
  • (C) Statement I is true but Statement II is false
  • (D) Both Statement I and Statement II are false

Question 59:

Consider the following spectral lines for atomic hydrogen :

A. First line of Paschen series

B. Second line of Balmer series

C. Third line of Paschen series

D. Fourth line of Bracket series

The correct arrangement of the above lines in ascending order of energy is :

  • (A) C \( < \) D \( < \) B \( < \) A
  • (B) A \( < \) B \( < \) C \( < \) D
  • (C) D \( < \) C \( < \) A \( < \) B
  • (D) D \( < \) A \( < \) C \( < \) B

Question 60:

Decomposition of A is a first order reaction at T(K) and is given by \( A(g) \rightarrow B(g) + C(g) \).

In a closed 1 L vessel, 1 bar A(g) is allowed to decompose at T(K). After 100 minutes, the total pressure was 1.5 bar. What is the rate constant (in \( min^{-1} \)) of the reaction ? (\( \log 2 = 0.3 \))

  • (A) \( 6.9 \times 10^{-4} \)
  • (B) \( 6.9 \times 10^{-1} \)
  • (C) \( 6.9 \times 10^{-2} \)
  • (D) \( 6.9 \times 10^{-3} \)

Question 61:

The correct order of the rate of the reaction for the following reaction with respect to nucleophiles is :
\( CH_3Br + Nu^\ominus \rightarrow CH_3Nu + Br^\ominus \)

  • (A) \( CH_3COO^\ominus > PhO^\ominus > ^\ominus OH > ClO_4^\ominus \)
  • (B) \( ClO_4^\ominus > CH_3COO^\ominus > ^\ominus OH > PhO^\ominus \)
  • (C) \( ^\ominus OH > PhO^\ominus > CH_3COO^\ominus > ClO_4^\ominus \)
  • (D) \( PhO^\ominus > ^\ominus OH > CH_3COO^\ominus > ClO_4^\ominus \)

Question 62:

Consider the following data :
\( \Delta_f H^\ominus (methane, g) = -X kJ mol^{-1} \)

Enthalpy of sublimation of graphite \( = Y kJ mol^{-1} \)

Dissociation enthalpy of \( H_2 = Z kJ mol^{-1} \)

The bond enthalpy of C-H bond is given by :

  • (A) \( \frac{X+Y+4Z}{2} \)
  • (B) \( \frac{X+Y+2Z}{4} \)
  • (C) \( \frac{-X+Y+Z}{4} \)
  • (D) \( X+Y+Z \)

Question 63:

Given below are two statements :

Statement I : Compound (X), shown below, dissolves in \( NaHCO_3 \) solution and has two chiral carbon atoms.


Statement II : Compound (Y), shown below, has two carbons with \( sp^3 \) hybridization, one carbon with \( sp^2 \) and one carbon with \( sp \) hybridization.



In the light of the above statements, choose the correct answer from the options given below :

  • (A) Statement I is false but Statement II is true
  • (B) Both Statement I and Statement II are false
  • (C) Both Statement I and Statement II are true
  • (D) Statement I is true but Statement II is false

Question 64:

Consider the following sequence of reactions. The number of bromine atom(s) in the final product (P) will be :


  • (A) 3
  • (B) 5
  • (C) 6
  • (D) 1

Question 65:

The correct order of reactivity of the following benzyl halides towards reaction with KCN is :


  • (A) b \( > \) a \( > \) c \( > \) d
  • (B) a \( > \) b \( > \) c \( > \) d
  • (C) a \( > \) b \( > \) d \( > \) c
  • (D) b \( > \) a \( > \) d \( > \) c

Question 66:

Given below are some of the statements about Mn and \( Mn_2O_7 \). Identify the correct statements.

A. Mn forms the oxide \( Mn_2O_7 \), in which Mn is in its highest oxidation state.

B. Oxygen stabilizes the Mn in higher oxidation states by forming multiple bonds with Mn.

C. \( Mn_2O_7 \) is an ionic oxide.

D. The structure of \( Mn_2O_7 \) consists of one bridged oxygen.

Choose the correct answer from the options given below :

  • (A) A, B and D Only
  • (B) A, C and D Only
  • (C) A, B and C Only
  • (D) A, B, C and D

Question 67:

On heating a mixture of common salt and \( K_2Cr_2O_7 \) in equal amount along with concentrated \( H_2SO_4 \) in a test tube, a gas is evolved. Formula of the gas evolved and oxidation state of the central metal atom in the gas respectively are :

  • (A) \( CrO_2Cl_2 \) and +6
  • (B) \( CrO_2Cl_2 \) and +5
  • (C) \( Cr_2O_2Cl_2 \) and +3
  • (D) \( Cr_2O_2Cl_2 \) and +6

Question 68:

Given below are two statements :

Statement I : The correct order in terms of atomic/ionic radii is \( Al > Mg > Mg^{2+} > Al^{3+} \).

Statement II : The correct order in terms of the magnitude of electron gain enthalpy is \( Cl > Br > S > O \).

In the light of the above statements, choose the correct answer from the options given below :

  • (A) Both Statement I and Statement II are false
  • (B) Both Statement I and Statement II are true
  • (C) Statement I is false but Statement II is true
  • (D) Statement I is true but Statement II is false

Question 69:

Match List - I with List - II.




Choose the correct answer from the options given below :

  • (A) A-II, B-I, C-IV, D-III
  • (B) A-I, B-IV, C-III, D-II
  • (C) A-III, B-I, C-II, D-IV
  • (D) A-III, B-I, C-IV, D-II

Question 70:

The correct increasing order of C-H(A), C-O(B), C=O(C) and C\(\equiv\)N(D) bonds in terms of covalent bond length is :

  • (A) A \( < \) D \( < \) C \( < \) B
  • (B) A \( < \) B \( < \) C \( < \) D
  • (C) D \( < \) C \( < \) B \( < \) A
  • (D) D \( < \) C \( < \) A \( < \) B

Question 71:

The first and second ionization constants of \(H_{2}X\) are \(2.5 \times 10^{-8}\) and \(1.0 \times 10^{-13}\) respectively. The concentration of \(X^{2-}\) in \(0.1\) M \(H_{2}X\) solution is \(\_\_\_\_\_\_ \times 10^{-13}\) M. (Nearest Integer)


Question 72:

The osmotic pressure of a living cell is 12 atm at 300 K. The strength of sodium chloride solution that is isotonic with the living cell at this temperature is \(\_\_\_\_\_\_\) g L\(^{-1}\). (Nearest integer)

Given: R = 0.08 L atm K\(^{-1}\) mol\(^{-1}\)

Assume complete dissociation of NaCl

(Given : Molar mass of Na and Cl are 23 and 35.5 g mol\(^{-1}\) respectively.)


Question 73:

Identify the metal ions among \(Co^{2+}, Ni^{2+}, Fe^{2+}, V^{3+}\) and \(Ti^{2+}\) having a spin-only magnetic moment value more than 3.0 BM. The sum of unpaired electrons present in the high spin octahedral complexes formed by those metal ions is \(\_\_\_\_\_\_\).


Question 74:

A substance 'X' (1.5 g) dissolved in 150 g of a solvent 'Y' (molar mass = 300 g mol\(^{-1}\)) led to an elevation of the boiling point by 0.5 K. The relative lowering in the vapour pressure of the solvent 'Y' is \(\_\_\_\_\_\_ \times 10^{-2}\). (nearest integer)

[Given : \(K_{b}\) of the solvent = 5.0 K kg mol\(^{-1}\)]

Assume the solution to be dilute and no association or dissociation of X takes place in solution.


Question 75:

MX is a sparingly soluble salt that follows the given solubility equilibrium at 298 K.

MX(s) \(\rightleftharpoons M^{+}(aq) + X^{-}(aq)\); \(K_{sp} = 10^{-10}\)

If the standard reduction potential for \(M^{+}(aq) + e^{-} \rightarrow M(s)\) is \((E^{\circ}_{M^{+}/M}) = 0.79\) V, then the value of the standard reduction potential for the metal/metal insoluble salt electrode \(E^{\circ}_{X^{-}/MX(s)/M}\) is \(\_\_\_\_\_\_\) mV. (nearest integer)

[Given : \(\frac{2.303 RT}{F} = 0.059\) V]


JEE Main 2026 Jan 21st Shift 2 Video Solutions