JEE Main 2026 Jan 24 Shift 2 question paper is available here with answer key and solutions. NTA conducted the first shift of the day on Jan 24, 2026, from 3 PM to 6 PM.

JEE Main 2026 24th Jan Shift 2 Question Paper with Solution PDF

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Based on initial analysis, JEE Main Jan 24th Shift 2 was Easy to Medium, where Mathematics remains the lengthiest section. Students can access the JEE Main Jan 24 Shift 2 official questions with answer keys here.
 

JEE Mains 2026 24th Jan Shift 2 Question Paper


Question 1:

The largest value of \(n\), for which \(40^n\) divides \(60!\), is

  • (A) 13
  • (B) 11
  • (C) 14
  • (D) 12

Question 2:

Consider the following three statements for the function \(f : (0,\infty) \rightarrow \mathbb{R}\) defined by
\[ f(x) = \left| \log_e x \right| - |x - 1| : \]



(I) \(f\) is differentiable at all \(x > 0\).

(II) \(f\) is increasing in \((0,1)\).

(III) \(f\) is decreasing in \((1,\infty)\).



Then,

  • (A) All (I), (II) and (III) are TRUE.
  • (B) Only (II) and (III) are TRUE.
  • (C) Only (I) and (III) are TRUE.
  • (D) Only (I) is TRUE.

Question 3:

Let \(P=[p_{ij}]\) and \(Q=[q_{ij}]\) be two square matrices of order \(3\) such that \(q_{ij}=2^{(i+j-1)}p_{ij}\) and \(\det(Q)=2^{10}\). Then the value of \(\det(\operatorname{adj}(\operatorname{adj} P))\) is

  • (A) 81
  • (B) 16
  • (C) 32
  • (D) 124

Question 4:

Let \(X=\{x\in\mathbb{N}:1\le x\le19\}\) and for some \(a,b\in\mathbb{R}\), \(Y=\{ax+b:x\in X\}\).
If the mean and variance of the elements of \(Y\) are \(30\) and \(750\) respectively, then the sum of all possible values of \(b\) is

  • (A) 60
  • (B) 80
  • (C) 100
  • (D) 20

Question 5:

Let the angles made with the positive \(x\)-axis by two straight lines drawn from the point \(P(2,3)\) and meeting the line \(x+y=6\) at a distance \(\sqrt{\frac{2}{3}}\) from the point \(P\) be \(\theta_1\) and \(\theta_2\). Then the value of \((\theta_1+\theta_2)\) is

  • (A) \(\dfrac{\pi}{6}\)
  • (B) \(\dfrac{\pi}{2}\)
  • (C) \(\dfrac{\pi}{12}\)
  • (D) \(\dfrac{\pi}{3}\)

Question 6:

Let \(a_1,a_2,a_3,a_4\) be an A.P. of four terms such that each term of the A.P. and its common difference are integers. If \(a_1+a_2+a_3+a_4=48\) and \(a_1^2a_2a_3a_4+1^4=361\), then the largest term of the A.P. is equal to

  • (A) 27
  • (B) 23
  • (C) 24
  • (D) 21

Question 7:

The letters of the word ``UDAYPUR'' are written in all possible ways with or without meaning and these words are arranged as in a dictionary. The rank of the word ``UDAYPUR'' is

  • (A) 1578
  • (B) 1579
  • (C) 1580
  • (D) 1581

Question 8:

The sum of all values of \(\alpha\), for which the shortest distance between the lines \(\dfrac{x+1}{\alpha}=\dfrac{y-2}{-1}=\dfrac{z-4}{-\alpha}\) and \(\dfrac{x}{\alpha}=\dfrac{y-1}{2}=\dfrac{z-1}{2\alpha}\) is \(\sqrt{2}\), is

  • (A) 6
  • (B) \(-6\)
  • (C) \(-8\)
  • (D) 8

Question 9:

If the domain of the function \(f(x)=\sin^{-1}\!\left(\dfrac{1}{x^2-2x-2}\right)\) is \((-\infty,\alpha)\cup[\beta,\gamma]\cup[\delta,\infty)\), then \(\alpha+\beta+\gamma+\delta\) is equal to

  • (A) 5
  • (B) 2
  • (C) 4
  • (D) 3

Question 10:

Let the length of the latus rectum of an ellipse \(\dfrac{x^2}{a^2}+\dfrac{y^2}{b^2}=1\) \((a>b)\) be \(30\).
If its eccentricity is the maximum value of the function \(f(t)=-\dfrac{3}{4}+2t-t^2\), then \((a^2+b^2)\) is equal to

  • (A) 276
  • (B) 516
  • (C) 256
  • (D) 496

Question 11:

Let \(\vec{a}=2\hat{i}-\hat{j}-\hat{k}\), \(\vec{b}=\hat{i}+3\hat{j}-\hat{k}\) and \(\vec{c}=2\hat{i}+\hat{j}+3\hat{k}\).
Let \(\vec{v}\) be the vector in the plane of \(\vec{a}\) and \(\vec{b}\), such that the length of its projection on the vector \(\vec{c}\) is \(\dfrac{1}{\sqrt{14}}\).
Then \(|\vec{v}|\) is equal to

  • (A) \(\dfrac{\sqrt{35}}{2}\)
  • (B) \(\dfrac{\sqrt{21}}{2}\)
  • (C) 7
  • (D) 13

Question 12:

Let \(f\) be a function such that \(3f(x)+2f\!\left(\dfrac{m}{19x}\right)=5x\), \(x\ne0\), where \(m=\displaystyle\sum_{i=1}^{9} i^2\).
Then \(f(5)-f(2)\) is equal to

  • (A) 18
  • (B) 9
  • (C) \(-9\)
  • (D) 36

Question 13:

Let \(f(\alpha)\) denote the area of the region in the first quadrant bounded by \(x=0\), \(x=1\), \(y^2=x\) and \(y=|\alpha x-5|-|1-\alpha x|+\alpha^2\).
Then \((f(0)+f(1))\) is equal to

  • (A) 12
  • (B) 9
  • (C) 7
  • (D) 14

Question 14:

The smallest positive integral value of \(a\), for which all the roots of \(x^4-ax^2+9=0\) are real and distinct, is equal to

  • (A) 3
  • (B) 9
  • (C) 7
  • (D) 4

Question 15:

Let \(\vec{a}=2\hat{i}-5\hat{j}+5\hat{k}\) and \(\vec{b}=\hat{i}-\hat{j}+3\hat{k}\).
If \(\vec{c}\) is a vector such that \(2(\vec{a}\times\vec{c})+3(\vec{b}\times\vec{c})=\vec{0}\) and \((\vec{a}-\vec{b})\cdot\vec{c}=-97\), then \(|\vec{c}\times\hat{k}|^2\) is equal to

  • (A) 193
  • (B) 218
  • (C) 205
  • (D) 233

Question 16:

Let \([t]\) denote the greatest integer less than or equal to \(t\).
If the function \[ f(x)= \begin{cases} b^2\sin\!\left[\dfrac{\pi}{2}\left[\dfrac{\pi}{2}(\cos x+\sin x)\cos x\right]\right], & x<0
\dfrac{\sin x-\dfrac{1}{2}\sin 2x}{x^3}, & x>0
a, & x=0 \end{cases} \]
is continuous at \(x=0\), then \(a^2+b^2\) is equal to

  • (A) \(\dfrac{3}{4}\)
  • (B) \(\dfrac{1}{2}\)
  • (C) \(\dfrac{5}{8}\)
  • (D) \(\dfrac{9}{16}\)

Question 17:

Let \[ f(x)=\int \frac{7x^{10}+9x^8}{(1+x^2+2x^9)^2}\,dx,\quad x>0, \]
and \[ A= \begin{bmatrix} 0 & 0 & 1
\frac14 & f'(1) & 1
\alpha & 4 & 1 \end{bmatrix}. \]
If \(B=\operatorname{adj}(\operatorname{adj} A)\), then the value of \(\alpha\) for which \(\det(B)=1\) is

  • (A) 1
  • (B) 2
  • (C) 3
  • (D) 4

Question 18:

The value of \[ \left(\frac13+\frac47\right) +\left(\frac1{3^2}+\frac13\times\frac47+\frac4{7^2}\right) +\left(\frac1{3^3}+\frac1{3^2}\times\frac47+\frac13\times\frac4{7^2}+\frac4{7^3}\right) +\cdots up to infinite terms is
\]

  • (A) \(\dfrac{7}{4}\)
  • (B) \(\dfrac{4}{3}\)
  • (C) \(\dfrac{6}{5}\)
  • (D) \(\dfrac{5}{2}\)

Question 19:

Let \(y=y(x)\) be a differentiable function in the interval \((0,\infty)\) such that \(y(1)=2\), and \[ \lim_{t\to x}\left(\frac{t^2y(x)-x^2y(t)}{x-t}\right)=3 for each x>0. \]
Then \(2y(2)\) is equal to

  • (A) 23
  • (B) 12
  • (C) 18
  • (D) 27

Question 20:

Let the image of parabola \(x^2=4y\) in the line \(x-y=1\) be \((y+a)^2=b(x-c)\), where \(a,b,c\in\mathbb{N}\).
Then \(a+b+c\) is equal to

  • (A) 4
  • (B) 6
  • (C) 12
  • (D) 8

Question 21:

The number of elements in the set \(\{x\in[0,180^\circ]: \tan(x+100^\circ)=\tan(x+50^\circ)\tan x\tan(x-50^\circ)\}\) is


Question 22:

Let \(z=(1+i)(1+2i)(1+3i)\cdots(1+ni)\), where \(i=\sqrt{-1}\).
If \(|z|^2=44200\), then \(n\) is equal to


Question 23:

Let \((h,k)\) lie on the circle \(C:x^2+y^2=4\) and the point \((2h+1,\,3k+2)\) lie on an ellipse with eccentricity \(e\).
Then the value of \(\dfrac{5}{e^2}\) is equal to


Question 24:

If \(f(x)\) satisfies the relation \[ f(x)=e^x+\int_0^1 (y+x e^x)f(y)\,dy, \]
then \(e+f(0)\) is equal to


Question 25:

Let \(S\) be a set of \(5\) elements and \(P(S)\) denote the power set of \(S\).
Let \(E\) be the event of choosing an ordered pair \((A,B)\) from \(P(S)\times P(S)\) such that \(A\cap B=\varnothing\).
If the probability of the event \(E\) is \(\dfrac{3^p}{2^q}\), where \(p,q\in\mathbb{N}\), then \(p+q\) is equal to


Question 26:

The binding energy for the following nuclear reactions are expressed in MeV.

\[ {}^{3}_{2}He + {}^{1}_{0}n \rightarrow {}^{4}_{2}He + 20 MeV \]
\[ {}^{4}_{2}He + {}^{1}_{0}n \rightarrow {}^{5}_{2}He - 0.9 MeV \]

If \( X_3, X_4, X_5 \) denote the stability of \( {}^{3}_{2}He, {}^{4}_{2}He \) and \( {}^{5}_{2}He \), respectively, then the correct order is:

  • (A) \( X_4 > X_5 > X_3 \)
  • (B) \( X_4 = X_5 = X_3 \)
  • (C) \( X_4 > X_5 < X_3 \)
  • (D) \( X_4 < X_5 < X_3 \)

Question 27:

The velocity (\(v\)) – distance (\(x\)) graph is shown in the figure. Which graph represents acceleration (\(a\)) versus distance (\(x\)) variation of this system?








Question 28:

A regular hexagon is formed by six wires each of resistance \( r \,\Omega \) and the corners are joined to the centre by wires of same resistance. If the current enters at one corner and leaves at the opposite corner, the equivalent resistance of the hexagon between the two opposite corners will be

  • (A) \( \dfrac{4}{5} r \)
  • (B) \( \dfrac{3}{4} r \)
  • (C) \( \dfrac{3}{5} r \)
  • (D) \( \dfrac{5}{8} r \)

Question 29:

Distance between an object and three times magnified real image is 40 cm. The focal length of the mirror used is ____ cm.

  • (A) \( -\dfrac{15}{2} \)
  • (B) \( -10 \)
  • (C) \( -20 \)
  • (D) \( -15 \)

Question 30:

In case of vertical circular motion of a particle by a thread of length \( r \), if the tension in the thread is zero at an angle \(30^\circ\) as shown in the figure, the velocity at the bottom point (A) of the vertical circular path is ( \( g \) = gravitational acceleration ).



  • (A) \( \sqrt{\dfrac{7}{2}gr} \)
  • (B) \( \sqrt{4gr} \)
  • (C) \( \sqrt{5gr} \)
  • (D) \( \sqrt{\dfrac{5}{2}gr} \)

Question 31:

The fifth harmonic of a closed organ pipe is found to be in unison with the first harmonic of an open pipe. The ratio of lengths of closed pipe to that of the open pipe is \( \frac{5}{x} \). The value of \( x \) is ____.

  • (A) 2
  • (B) 3
  • (C) 4
  • (D) 1

Question 32:

Three parallel plate capacitors each with area \(A\) and separation \(d\) are filled with two dielectric (\(k_1\) and \(k_2\)) in the following fashion. (\(k_1 > k_2\)) Which of the following is true?


  • (A) \( C_B > C_C > C_A \)
  • (B) \( C_C > C_A > C_B \)
  • (C) \( C_C > C_B > C_A \)
  • (D) \( C_A > C_C > C_B \)

Question 33:

Two identical circular loops \(P\) and \(Q\) each of radius \(r\) are lying in parallel planes such that they have common axis. The current through \(P\) and \(Q\) are \(I\) and \(4I\) respectively in clockwise direction as seen from \(O\). The net magnetic field at \(O\) is:


  • (A) \( \dfrac{\mu_0 I}{4\sqrt{2}r} \) towards \(Q\)
  • (B) \( \dfrac{\mu_0 I}{4\sqrt{2}r} \) towards \(P\)
  • (C) \( \dfrac{3\mu_0 I}{4\sqrt{2}r} \) towards \(P\)
  • (D) \( \dfrac{3\mu_0 I}{4\sqrt{2}r} \) towards \(Q\)

Question 34:

10 mole of an ideal gas is undergoing the process shown in the figure. The heat involved in the process from \(P_1\) to \(P_2\) is \( \alpha \) Joule \((P_1 = 21.7 Pa,\; P_2 = 30 Pa,\; C_v = 21 J/K·mol,\; R = 8.3 J/mol·K)\). The value of \( \alpha \) is ____.

  • (A) 15
  • (B) 21
  • (C) 28
  • (D) 24

Question 35:

In a vernier callipers, 50 vernier scale divisions are equal to 48 main scale divisions. If one main scale division = 0.05 mm, then the least count of the vernier callipers is ____ mm.

  • (A) 0.02
  • (B) 0.005
  • (C) 0.002
  • (D) 0.05

Question 36:

A flexible chain of mass \(m\) hangs between two fixed points at the same level. The inclination of the chain with the horizontal at the two points of support is \(30^\circ\). Considering the equilibrium of each half of the chain, the tension of the chain at the lowest point is ____.

  • (A) \( \sqrt{3}mg \)
  • (B) \( \dfrac{\sqrt{3}}{2}mg \)
  • (C) \( mg \)
  • (D) \( \dfrac{1}{2}mg \)

Question 37:

Identify the correct truth table of the given logic circuit.





Question 38:

A moving coil galvanometer of resistance \(100\,\Omega\) shows a full scale deflection for a current of \(1\,mA\). The value of resistance required to convert this galvanometer into an ammeter, showing full scale deflection for a current of \(5\,mA\), is ____ \(\Omega\).

  • (A) 25
  • (B) 2.5
  • (C) 10
  • (D) 0.5

Question 39:

A point source is kept at the center of a spherically enclosed detector. If the volume of the detector is increased by 8 times, the intensity will

  • (A) increase by 8 times
  • (B) increase by 64 times
  • (C) decrease by 4 times
  • (D) decrease by 8 times

Question 40:

Five persons \(P_1, P_2, P_3, P_4\) and \(P_5\) recorded object distance (\(u\)) and image distance (\(v\)) using same convex lens having power \(+5\) D as (25,96), (30,62), (35,37), (45,35) and (50,32) respectively. Identify correct statement.

  • (A) Readings recorded by \(P_4\) and \(P_5\) persons are incorrect
  • (B) Readings recorded by \(P_3\) and \(P_2\) persons are incorrect
  • (C) Readings recorded by all persons are correct
  • (D) Readings recorded by \(P_3\) persons are incorrect

Question 41:

In the Young's double slit experiment the intensity produced by each one of the individual slits is \(I_0\). The distance between two slits is \(2\,mm\). The distance of screen from slits is \(10\,m\). The wavelength of light is \(6000\,\AA\). The intensity of light on the screen in front of one of the slits is ____.

  • (A) \( I_0 \)
  • (B) \( 2I_0 \)
  • (C) \( \dfrac{I_0}{2} \)
  • (D) \( 4I_0 \)

Question 42:

A cubical block of density \( \rho_b = 600\,kg/m^3 \) floats in a liquid of density \( \rho_l = 900\,kg/m^3 \). If the height of block is \(H = 8.0\,cm\), then height of the submerged part is ____ cm.

  • (A) 5.3
  • (B) 6.3
  • (C) 7.3
  • (D) 4.3

Question 43:

The reading of the ammeter (\(A\)) in steady state in the following circuit (assuming negligible internal resistance of the ammeter) is ____ A.

  • (A) 2
  • (B) \( \dfrac{1}{2} \)
  • (C) 0
  • (D) 1

Question 44:

A thin uniform rod (\(X\)) of mass \(M\) and length \(L\) is pivoted at a height \( \left(\dfrac{L}{3}\right) \) as shown in the figure. The rod is allowed to fall from a vertical position and lie horizontally on the table. The angular velocity of this rod when it hits the table top is ____. (\(g\) = gravitational acceleration)



  • (A) \( \sqrt{\dfrac{3g}{2L}} \)
  • (B) \( \dfrac{3}{\sqrt{2}} \sqrt{\dfrac{g}{L}} \)
  • (C) \( \sqrt{\dfrac{3g}{L}} \)
  • (D) \( \dfrac{1}{\sqrt{2}} \sqrt{\dfrac{g}{L}} \)

Question 45:

When a light of a given wavelength falls on a metallic surface the stopping potential for photoelectrons is \(3.2\ V\). If a second light having wavelength twice of the first light is used, the stopping potential drops to \(0.7\ V\). The wavelength of the first light is ____ m.

  • (A) \(2.2 \times 10^{-8}\)
  • (B) \(3.1 \times 10^{-7}\)
  • (C) \(2.5 \times 10^{-7}\)
  • (D) \(2.9 \times 10^{-8}\)

Question 46:

A soap bubble of surface tension \(0.04\,N/m\) is blown to a diameter of \(7\,cm\). If \((15000 - x)\,\muJ\) of work is done in blowing it further to make its diameter \(14\,cm\) \((\pi = 22/7)\), then the value of \(x\) is ____.


Question 47:

A uniform solid cylinder of length \(L\) and radius \(R\) has moment of inertia about its axis equal to \(I_1\). A small co-centric cylinder of length \(L/2\) and radius \(R/3\) carved from it has moment of inertia about its axis equal to \(I_2\). The ratio \(I_1/I_2\) is ____.


Question 48:

In a meter bridge experiment to determine the value of unknown resistance, first the resistances \(2\,\Omega\) and \(3\,\Omega\) are connected in the left and right gaps of the bridge and the null point is obtained at a distance \(l\) cm from the left end. Now, when an unknown resistance \(x\,\Omega\) is connected in parallel to \(3\,\Omega\), the null point is shifted by \(10\,cm\) to the right. The value of \(x\) is ____ \(\Omega\).


Question 49:

When \(300\,J\) of heat is given to an ideal gas with \(C_p = \dfrac{7}{2}R\), its temperature rises from \(20^\circC\) to \(50^\circC\) keeping its volume constant. The mass of the gas is (approximately) ____ g. \((R = 8.314\,J/mol·K)\)


Question 50:

A point charge \(q = 1\,\muC\) is located at a distance \(2\,cm\) from one end of a thin insulating wire of length \(10\,cm\) having a charge \(Q = 24\,\muC\), distributed uniformly along its length, as shown in the figure. Force between \(q\) and wire is ____ N.


(Use: \(\dfrac{1}{4\pi\varepsilon_0} = 9 \times 10^9\,N·m^2/C^2\))




Question 51:

In the group analysis of cations, Ba\(^{2+}\) \& Ca\(^{2+}\) are precipitated respectively as

  • (A) hydroxide \& carbonate
  • (B) sulphide \& sulphide
  • (C) chromate \& sulphide
  • (D) carbonate \& carbonate

Question 52:

Given below are two statements:


Statement I: The dipole moment of R–CN is greater than R–NC and R–NC can undergo hydrolysis under acidic medium to produce R–COOH.


Statement II: R–CN hydrolyses under acidic medium to produce a compound which on treatment with SOCl\(_2\), followed by the addition of NH\(_3\) gives another compound (X). This compound (X) on treatment with NaOCl/NaOH gives a product, that on treatment with CHCl\(_3\)/KOH/\(\Delta\) produces R–NC.



In the light of the above statements, choose the correct answer from the options given below.

  • (A) Both Statement I and Statement II are true
  • (B) Both Statement I and Statement II are false
  • (C) Statement I is true but Statement II is false
  • (D) Statement I is false but Statement II is true

Question 53:

``X'' is an oxoanion of the lightest element of group 17 (in the periodic table). The metal is in +6 oxidation state in ``X''. The color of the potassium salt of X is

  • (A) purple
  • (B) green
  • (C) orange
  • (D) yellow

Question 54:

Choose the INCORRECT statement

  • (A) Carbon exhibits negative oxidation states along with +4 and +2.
  • (B) CO\(_2\) is the most acidic oxide among the dioxides of group 14 elements.
  • (C) Among the isotopes of carbon, \(^{13}\)C is a radioactive isotope.
  • (D) Carbon cannot exceed its covalency more than four.

Question 55:

Two liquids A and B form an ideal solution at temperature T K. At T K, the vapour pressures of pure A and pure B are 55 and 15 kPa respectively. What is the mole fraction of A in solution of A and B in equilibrium with a vapour in which the mole fraction of A is 0.8?

  • (A) 0.340
  • (B) 0.663
  • (C) 0.480
  • (D) 0.5217

Question 56:

The number of possible tripeptides formed involving alanine (ala), glycine (gly) and valine (val), where no amino acid has been used more than once is

  • (A) 3
  • (B) 6
  • (C) 8
  • (D) 4

Question 57:

One mole of Cl\(_2\)(g) was passed into 2 L of cold 2 M KOH solution. After the reaction, the concentrations of Cl\(^-\), ClO\(^-\) and OH\(^-\) are respectively (assume volume remains constant)

  • (A) 1 M, 1 M, 1 M
  • (B) 0.5 M, 0.5 M, 0.5 M
  • (C) 0.5 M, 0.5 M, 1 M
  • (D) 0.75 M, 0.75 M, 1 M

Question 58:

Given below are two statements regarding conformations of n-butane. Choose the correct option.


  • (A) Both Statement I and Statement II are false
  • (B) Statement I is false but Statement II is true
  • (C) Statement I is true but Statement II is false
  • (D) Both Statement I and Statement II are true

Question 59:

At 298 K, the mole percentage of N\(_2\)(g) in air is 80%. Water is in equilibrium with air at a pressure of 10 atm. What is the mole fraction of N\(_2\)(g) in water at 298 K? (\(K_H\) for N\(_2\) = \(6.5 \times 10^7\) mm Hg)

  • (A) \(9.35 \times 10^{-5}\)
  • (B) \(1.17 \times 10^{-4}\)
  • (C) \(9.35 \times 10^{5}\)
  • (D) \(1.23 \times 10^{-7}\)

Question 60:

From the following, how many compounds contain at least one secondary alcohol?



  • (A) Three
  • (B) Four
  • (C) Five
  • (D) Two

Question 61:

The wavelength of light absorbed for the following complexes are in the order

[Co(NH\(_3\))\(_6\)]\(^{3+}\) (I), [Co(H\(_2\)O)\(_6\)]\(^{3+}\) (II), [Co(CN)\(_6\)]\(^{3-}\) (III), [Co(NH\(_3\))\(_5\)(H\(_2\)O)]\(^{3+}\) (IV), [CoF\(_6\)]\(^{3-}\) (V)

  • (A) III \(<\) I \(<\) IV \(<\) II \(<\) V
  • (B) III \(<\) I \(<\) II \(<\) IV \(<\) V
  • (C) III \(<\) IV \(<\) I \(<\) II \(<\) V
  • (D) III \(<\) I \(<\) IV \(<\) V \(<\) II

Question 62:

Consider the following gaseous equilibrium in a closed container of volume \(V\) at temperature \(T\):

P\(_2\)(g) + Q\(_2\)(g) \(\rightleftharpoons\) 2PQ(g)

Initially, 2 moles each of P\(_2\)(g), Q\(_2\)(g) and PQ(g) are present at equilibrium. One mole each of P\(_2\) and Q\(_2\) are added. The number of moles of P\(_2\), Q\(_2\) and PQ at the new equilibrium respectively are

  • (A) 1.21, 2.24, 1.56
  • (B) 2.67, 2.67, 2.67
  • (C) 1.66, 1.66, 1.66
  • (D) 2.56, 1.62, 2.24

Question 63:

Given below are two statements:


Statement I: Cross aldol condensation between two different aldehydes will always produce four different products.

Statement II: When semicarbazide reacts with a mixture of benzaldehyde and acetophenone under optimum pH, it forms a condensation product with acetophenone only.

  • (A) Statement I is false but Statement II is true
  • (B) Both Statement I and Statement II are false
  • (C) Statement I is true but Statement II is false
  • (D) Both Statement I and Statement II are true

Question 64:

The wavelength of spectral line obtained in the spectrum of Li\(^{2+}\) ion, when the transition takes place between two levels whose sum is 4 and difference is 2, is

  • (A) \(1.14 \times 10^{-7}\) cm
  • (B) \(2.28 \times 10^{-7}\) cm
  • (C) \(2.28 \times 10^{-6}\) cm
  • (D) \(1.14 \times 10^{-6}\) cm

Question 65:

The heat of atomisation of methane and ethane are \(x\) kJ mol\(^{-1}\) and \(y\) kJ mol\(^{-1}\) respectively. The longest wavelength (\(\lambda\)) of light capable of breaking the C–C bond can be expressed in SI unit as:

  • (A) \(\dfrac{hc}{1000}\left(\dfrac{y-6x}{4}\right)^{-1}\)
  • (B) \(\dfrac{N_A hc}{250(y-6x)}\)
  • (C) \(N_A hc\left(\dfrac{y-6x}{4}\right)^{-1}\)
  • (D) \(\dfrac{N_A hc}{250(4y-6x)}\)

Question 66:

Pair of species among the following having same bond order as well as paramagnetic character will be:

  • (A) O\(_2^-\), N\(_2^-\)
  • (B) O\(_2^+\), N\(_2^{2-}\)
  • (C) O\(_2^-\), N\(_2^+\)
  • (D) O\(_2^+\), N\(_2^-\)

Question 67:

The unsaturated ether on acidic hydrolysis produces carbonyl compounds as shown below. Based on this, predict the solution/reagent that will help to distinguish "P" and "Q" obtained in the reaction.

  • (A) 2,4-DNP reagent
  • (B) Saturated NaHSO\(_3\) solution
  • (C) Fehling solution
  • (D) Lucas reagent

Question 68:

Find out the statements which are not true.


A. Resonating structures with more covalent bonds and less charge separation are more stable.

B. In electromeric effect, an unsaturated system shows +E effect with nucleophile and –E effect with electrophile.

C. Inductive effect is responsible for high melting point, boiling point and dipole moment of polar compounds.

D. The greater the number of alkyl groups attached to the doubly bonded carbon atoms, higher is the heat of hydrogenation.

E. Stability of carbanion increases with increase in s-character of the carbon carrying negative charge.

  • (A) B, D \& E only
  • (B) A, D \& E only
  • (C) B \& D only
  • (D) A, C \& D only

Question 69:

The correct order of C, N, O and F in terms of second ionisation potential is

  • (A) C \(<\) N \(<\) F \(<\) O
  • (B) F \(<\) N \(<\) C \(<\) O
  • (C) C \(<\) O \(<\) N \(<\) F
  • (D) C \(<\) F \(<\) N \(<\) O

Question 70:

A student has planned to prepare acetanilide from aniline using acetic anhydride. The student has started from 9.3 g of aniline. However, the student has managed to obtain 11 g of dry acetanilide. The % yield of this reaction is

  • (A) 97.5%
  • (B) 81.5%
  • (C) 59.5%
  • (D) 72.5%

Question 71:

The half-life of \(^{65}\)Zn is 245 days. After \(x\) days, 75% of the original activity remained. The value of \(x\) in days is \underline{\hspace{1.5cm (Nearest integer).

(Given: \(\log 3 = 0.4771\) and \(\log 2 = 0.3010\))


Question 72:

Molar conductivity of a weak acid HQ of concentration 0.18 M was found to be \(\dfrac{1}{30}\) of the molar conductivity of another weak acid HZ with concentration 0.02 M. If \(\alpha_Q\) happened to be equal with \(\alpha_Z\), then the difference of the pK\(_a\) values of the two weak acids (pK\(_a\)(HQ) – pK\(_a\)(HZ)) is \underline{\hspace{1cm (Nearest integer).

(Given: degree of dissociation (\(\alpha \ll 1\) for both weak acids, \(\lambda^\circ\) : limiting molar conductivity of ions)


Question 73:

A chromium complex with formula CrCl\(_3\cdot\)6H\(_2\)O has a spin only magnetic moment value of 3.87 BM and its solution conductivity corresponds to 1:2 electrolyte. 2.75 g of the complex solution was initially passed through a cation exchanger. The solution obtained after the process was reacted with excess of AgNO\(_3\). The amount of AgCl formed in the above process is \hspace{1cm g (Nearest integer).

(Given: Molar mass in g mol\(^{-1\) Cr: 52; Cl: 35.5; Ag:108; O:16; H:1)


Question 74:

0.25 g of an organic compound “A” containing carbon, hydrogen and oxygen was analysed using combustion method. The increase in mass of CaCl\(_2\) tube and potash tube at the end of the experiment was found to be 0.15 g and 0.1837 g respectively. The percentage of oxygen in compound A is \underline{\hspace{1cm% (Nearest integer).


Question 75:

Grignard reagent RMgBr (P) reacts with water and forms a gas (Q). One gram of Q occupies 1.4 dm\(^3\) at STP. (P) on reaction with dry ice in dry ether followed by H\(_3\)O\(^+\) forms compound (Z). 0.1 mole of (Z) will weigh \underline{\hspace{1cm g (Nearest integer).

JEE Main 2026 Jan 24th Shift 2 Video Solutions