JEE Main 2026 April 5 Shift 1 chemistry question paper is available here with answer key and solutions. NTA conducted the second shift of the day on April 5, 2026, from 9:00 AM to 12:00 PM.

  • The JEE Main Chemistry Question Paper contains a total of 25 questions.
  • Each correct answer gets you 4 marks while incorrect answers gets you a negative mark of 1.

Candidates can download the JEE Main 2026 April 5 Shift 1 chemistry question paper along with detailed solutions to analyze their performance and understand the exam pattern better.

JEE Main 2026 April 5 Shift 1 Chemistry Question Paper with Solution PDF

JEE Mains 2026 April 5 Shift 1 Chemistry Question Paper with Solutions

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Question 1:

For a first order reaction : \[ A(g) \rightarrow B(g) + C(g) \]
If initial pressure is \( P_0 \) and total pressure at time \( t \) is \( P_t \), then the expression of rate constant \( K \) is:

  • (A) \( K = \frac{1}{t}\ln\left(\frac{P_0}{P_0 - P_t}\right) \)
  • (B) \( K = \frac{1}{t}\ln\left(\frac{P_0}{2P_0 - P_t}\right) \)
  • (C) \( K = \frac{1}{t}\ln\left(\frac{2P_0}{P_0 - P_t}\right) \)
  • (D) \( K = \frac{1}{t}\frac{2P_0}{2P_0 - P_t} \)

Question 2:

On heating \(2.76\,g\) of \( Ag_2CO_3 (s) \), some solid residue is left behind. Determine the mass of residue left.

  • (A) \(2.16\,g\)
  • (B) \(4.32\,g\)
  • (C) \(2.32\,g\)
  • (D) \(1.08\,g\)

Question 3:

Determine mole fraction of water in an aqueous solution of urea having \(10%\) w/w urea.

  • (A) \(0.967\)
  • (B) \(0.086\)
  • (C) \(0.323\)
  • (D) \(0.867\)

Question 4:

For reaction \( A \rightleftharpoons B + C \)
\[ \begin{array}{|c|c|c|c|} \hline \log K_p & 3.5 & 2.5 & 1.5
\hline \frac{1}{T}\,(K^{-1}) & 0.04 & 0.05 & 0.06
\hline \end{array} \]

Calculate \( \dfrac{\Delta H}{R} \) (in Kelvin) based on above data. (In nearest integer)


Question 5:

If solubility of sparingly soluble salt \( M_3A_2(s) \) is \(x\) gm/litre and \(y\) is the molar mass (in gm/mole) of the salt, then determine the value of \( \dfrac{[A^{3-}]}{K_{sp}} \).

  • (A) \( \dfrac{1}{36}\dfrac{y^4}{x^4} \)
  • (B) \( \dfrac{1}{54}\dfrac{y^4}{x^4} \)
  • (C) \( \dfrac{1}{54}\dfrac{x^4}{y^4} \)
  • (D) \( \dfrac{1}{36}\dfrac{x^3}{y^3} \)

Question 6:

Half life of first order reaction is \(6.93\) min. What is the time required (in min.) to complete \(99%\) of reaction? \([\ln2 = 0.693]\)

  • (A) \(23.06\)
  • (B) \(46.06\)
  • (C) \(13.86\)
  • (D) \(20.79\)

Question 7:

Three solutions (A, B and C) are prepared according to given diagrams
\[ Solution A: 0.1M,\;10\,ml HCl(aq) + 0.1M,\;25\,ml Ca(OH)_2(aq) \]
\[ Solution B: 0.1M,\;10\,ml H_2SO_4(aq) + 0.1M,\;10\,ml Ca(OH)_2(aq) \]
\[ Solution C: 0.1M,\;10\,ml H_2SO_4(aq) + 0.1M,\;10\,ml NaOH(aq) \]

If pH of solutions A, B and C are respectively \(pH_1\), \(pH_2\) and \(pH_3\), then correct option will be:

  • (A) \(pH_3 < pH_2 < pH_1\)
  • (B) \(pH_3 > pH_2 > pH_1\)
  • (C) \(pH_3 > pH_1 > pH_2\)
  • (D) \(pH_1 < pH_3 < pH_2\)

Question 8:

From the following, number of compounds with \(sp^3d\) hybridisation are:
\[ XeF_4,\; ICl_4^-,\; ICl_2^-,\; XeF_5^-,\; SF_4,\; XeF_2,\; ClF_3,\; BrF_5,\; NH_4^+ \]


Question 9:

Which of the following property about Interstitial compound is INCORRECT?

  • (A) They have high melting point, higher than those of pure metals.
  • (B) They retain metallic conductivity
  • (C) They are ionic in nature & are soft.
  • (D) They are chemically inert.

Question 10:

Statement I : Sodium and Potassium dichromate are used as a primary standard in redox titrations.

Statement II : Phenolphthalein is weakly basic in nature hence it dissociates in acidic medium.

  • (A) Both Statement I and Statement II are correct
  • (B) Statement I is correct but Statement II is incorrect.
  • (C) Statement I is incorrect but Statement II is correct.
  • (D) Both Statement I and Statement II are incorrect

Question 11:

Consider the following statements

(A) Ground state electronic configuration of Cr is \([Ar]\,4s^1 3d^5\)

(B) Size of \(2p_x\) orbital is smaller than \(3p_y\)

(C) Heisenberg uncertainty principle is applicable only for electron.

(D) (Energy of \(2s\))\(_{Hydrogen}\) = (Energy of \(2s\))\(_{Lithium}\)


The correct statements are

  • (A) A & C
  • (B) B & D
  • (C) A & B
  • (D) C & D

Question 12:

Statement I : An electron in \( e_g \) causes destabilization of \(0.6\,\Delta_o\) and an electron in \( t_{2g} \) causes stabilization of \(0.4\,\Delta_o\) as per CFT.

Statement II : All d-orbitals of transition elements are degenerate in absence of ligands but splitting occurs in presence of ligands.

  • (A) Both Statement I and Statement II are correct
  • (B) Statement I is correct but Statement II is incorrect.
  • (C) Statement I is incorrect but Statement II is correct.
  • (D) Both Statement I and Statement II are incorrect

Question 13:

Consider the statements.

(A) \( N - N > P - P \) (Bond energy of single bond)

(B) All oxidation states of N lying between \(+1\) and \(+4\) tend to disproportionate in acidic medium.

(C) Maximum covalency of nitrogen is 4

(D) Nitrogen can form \(d\pi - p\pi\) bond with itself and other elements.

(E) Nitrogen has maximum density in its group due to its small size


The incorrect statements are:

  • (A) A, B & D
  • (B) A, D & E
  • (C) B, C & E
  • (D) A, C & E

Question 14:

Compare the energy of orbitals for multielectronic species :

(A) \(n = 3, \ell = 0, m = 0\)

(B) \(n = 3, \ell = 1, m = -1\)

(C) \(n = 4, \ell = 2, m = 0\)

(D) \(n = 3, \ell = 2, m = 1\)

  • (1) \(A > B > C > D\)
  • (2) \(A > B > D > C\)
  • (3) \(C > B > D > A\)
  • (4) \(C > D > B > A\)

Question 15:

Statement-I : The electronegativity order in F, O, N is \(F > O > N\).

Statement-II : Oxidation state of O in \(OF_2\) is \(+2\) and in \(Na_2O\) is \(-2\).

Choose the correct option.

  • (1) Both statement-I & statement-II are correct.
  • (2) Both statement-I & statement-II are incorrect.
  • (3) Statement-I is correct & statement-II is incorrect.
  • (4) Statement-I is incorrect & statement-II is correct.

Question 16:

Select the correct statements :

(a) Glucose has 2 anomeric forms.

(b) Both forms have difference in configuration at \(C_1\) carbon.

(c) \(\alpha\)-form has more melting point than \(\beta\)-form.

(d) Specific rotation of \(\alpha\)-form is \(+19^\circ\) and \(\beta\)-form has \(+112^\circ\).

(e) \(\alpha\)-form crystallises at \(307^\circ\) and \(\beta\)-form crystallises at \(371^\circ\).

  • (1) b, c is correct
  • (2) a, b and e is correct
  • (3) a, b is correct
  • (4) a, b, d, e is correct

Question 17:

0.4 gm organic compound is subjected to estimation of sulphur by Carius method. In the process \(0.6\) gm of \(BaSO_4\) was formed. Find % of sulphur (nearest integer).

  • (A) 18
  • (B) 21
  • (C) 24
  • (D) 27

Question 18:

Benzene reacts with propyl chloride in presence of \(AlCl_3\) to give product \(X\). Mark correct statement(s) for the given reaction.




(a) One of the intermediate is formed due to rearrangement.

(b) Major product is n-propylbenzene.

(c) Polysubstitution of substrate is also possible.

(d) Electron releasing group decreases rate of reaction.

  • (1) b and d are correct
  • (2) a and c are correct
  • (3) b and c are correct
  • (4) a and d are correct.

Question 19:

The % increase in oxygen in steam volatile product with respect to phenol is ______ \(10^{-1}%\).

  • (A) 125
  • (B) 150
  • (C) 175
  • (D) 200
Correct Answer: (3) 175
View Solution




Concept:

Phenol undergoes electrophilic substitution with dilute nitric acid to form a mixture of o-nitrophenol and \textit{p-nitrophenol. Among these products, \textit{o-nitrophenol is steam volatile due to intramolecular hydrogen bonding. Therefore, the steam volatile product considered here is o-nitrophenol.

Step 1: Write the reaction.
\[ Phenol \xrightarrow{Dil. HNO_3 o-Nitrophenol + p-Nitrophenol \]
\[ o-Nitrophenol is steam volatile \]

Step 2: Calculate % oxygen in phenol.

Molecular formula of phenol: \[ C_6H_6O \]

Molar mass: \[ 6(12) + 6(1) + 16 = 94 \]

Mass of oxygen in phenol \(=16\).
\[ %O_{phenol}= \frac{16}{94}\times100 \]
\[ %O_{phenol} = 17.02% \]

Step 3: Calculate % oxygen in o-nitrophenol.

Molecular formula: \[ C_6H_5NO_3 \]

Molar mass: \[ 6(12) + 5(1) + 14 + 3(16) = 139 \]

Mass of oxygen \(=3\times16=48\).
\[ %O= \frac{48}{139}\times100 \]
\[ %O = 34.53% \]

Step 4: Calculate increase in oxygen percentage.
\[ Increase = 34.53 - 17.02 \]
\[ = 17.51 \approx 17.5 \]

Given answer format is \(10^{-1}%\):
\[ 17.5 \times 10^{-1} = 175 \]
\[ \boxed{175} \] Quick Tip: o-Nitrophenol is steam volatile due to intramolecular hydrogen bonding, while p-nitrophenol forms intermolecular hydrogen bonding and is not steam volatile.


Question 20:

Hydrocarbon (P) on reductive ozonolysis gives products which give positive iodoform test and on acidification produces the compound shown. Identify the structure of (P).

  • (A) Structure (1)
  • (B) Structure (2)
  • (C) Structure (3)
  • (D) Structure (4)

Question 21:

Compound A is formed when compound B reacts with reagent (R). When compound C reacts with the same reagent (R), the product formed will be (S). Identify reagent (R) and product (S).


  • (1) Structure 1
  • (2) Structure 2
  • (3) Structure 3
  • (4) Structure 4

Question 22:

Which amongst the following will give benzyl isocyanide as a major product?

  • (1) i & ii
  • (2) ii & iii
  • (3) i & iii
  • (4) ii & iv

Question 23:

Statement 1: Stability of carbanion follows the order shown.




Statement 2: Allylic and benzylic carbanion stability is based on inductive effect and not resonance effect.

  • (1) Both Statement I and Statement II are correct
  • (2) Statement I is correct but Statement II is incorrect
  • (3) Statement I is incorrect but Statement II is correct
  • (4) Both Statement I and Statement II are incorrect

JEE Main 2026 Chemistry Exam Pattern

Particulars Details
Exam Mode Online (Computer-Based Test)
Paper B.E./B.Tech
Medium of Exam 13 languages: English, Hindi, Gujarati, Bengali, Tamil, Telugu, Kannada, Marathi, Malayalam, Odia, Punjabi, Assamese, Urdu
Type of Questions Multiple Choice Questions (MCQs) + Numerical Value Questions
Total Marks 100 marks
Marking Scheme +4 for correct answer & -1 for incorrect MCQ and Numerical Value-based Questions
Total Questions 25 Questions

JEE Main 2026 Chemistry Revision